Reactions of N-Substituted Pyrrole Derivatives and Related Compounds with 3,4,5,6-Tetrachloro-1,2-benzoquinone
スポンサーリンク
概要
- 論文の詳細を見る
While furans nad oxazoles give [4+2]-type cycloaddition products in the reactions with 3,4,5,6-tetrachloro-1,2-benzoquinone, 1-mehyl, 1-phenyl, and 1-dimethylaminopyrrole and 1-methylindole afforded keto-enol-type substitution products under the same reaction conditions. The reaction of pyrroles proceeds via nucleophilic attack of the pyrroles on the o-quinoid ring. The difference in the reaction of pyrroles from that of the other heterocycles is considered to be attributable to the degree of aromaticity of these compounds.
- 公益社団法人日本薬学会の論文
- 1988-12-25
著者
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斉藤 勝裕
Department of Applied Chemistry, Nagoya Institute of Technology
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斉藤 勝裕
Department Of Applied Chemistry Nagoya Institute Of Technology
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高橋 憲助
Department Of Applied Chemistry Nagoya Institute Of Technology
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堀江 洋一
Department Of Applied Chemistry Nagoya Institute Of Technology
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- Reactions of N-Substituted Pyrrole Derivatives and Related Compounds with 3,4,5,6-Tetrachloro-1,2-benzoquinone
- Aromatization and Hydrogen-Shift of 7-Substituted 1,3,5-Cycloheptatrienes in the Presence of Palladium(II) Acetate
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