Oxidation of the Hydrogenation Products of Lycorenine and Homolycorine.

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概要

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• Oxidation of α-deoxydihydrolycorenine (I) with potassium dichromate in sulfuric acid gave α-dihydrohomolycorine and with potassium permanganate α-deoxydihydro-2-oxolycorenine (V) which reverted to I on treatment with lithium aluminum hydride. β-Deoxydihydrolycorenine (II) gave with potassium permanganate β-dihydrolycorenine together with β-dihydrohomolycorine which constituted the sole product of dichromate oxidation of (II) and gave on further oxidation with permanganate the N-formyl derivative (XII) which was converted into β-dihydro-7-oxopluviine (XI) on treatment with alcoholic sodium hydroxide. α-Dihydrolycorenine (XIII) was obtained only by reduction of α-dihydrohomolycorine with lithium aluminum hydride under controlled conditions.

• 公益社団法人日本薬学会の論文
• 1964-04-25

著者

• 上尾 庄次郎

  Faculty of Pharmaceutical Sciences, Kobe Gakuin University

• 北川 常広

  Faculty Of Pharmaceutical Sciences Nagasaki University

• 上尾 庄次郎

  Faculty Of Pharmaceutical Sciences Kobe Gakuin University

• 山本 義公

  Pharmaceutical Faculty, University of Nagasaki

• 山本 義公

  Faculty of Pharmaceutical Sciences, Kyoto University

• 山本 義公

  Faculty Of Pharmaceutical Sciences Kyoto University

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