Studies on N-Substituted Nortropane Derivatives. III. The Infrared Spectra of N-Substituted 3α- and 3β-Nortropanols.
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概要
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The infrared spectra of nine N-substituted 3-nortropanones were measured and their carbonyl frequency in 3-position was compared with that of other ketones located in a different position in tropane skeleton. Infrared spectra of several N-substituted 3-nortropanols were measured, especially in C-O stretching region. A regular difference between 3α- and 3β-ols was observed. Some of the N-substituted 3-nortropanones were reduced with sodium borohydride and the structures of resulting bases were presumed from their infrared spectra.
- 公益社団法人日本薬学会の論文
- 1961-04-25
著者
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内丸 文彦
Research Institute, Daiichi Seiyaku Co., Ltd.
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内丸 文彦
Research Institute Daiichi Seiyaku Co. Ltd.
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