Thermolysis of Taxinine and Taxinine H. Allylic Rearrangement of the Ester Moiety in the C-Ring
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概要
- 論文の詳細を見る
Thermolysis of taxinine and taxinine H, esters of 2α, 9α, 10β-triacetoxy-8β, 12,15α, 15β-tetramethyl-4-methylene-13-oxotricyclo[9.3.1.0^<3,8>] pentadec-11-en-5α-ol, resulted in the smooth formation of the corresponding 4-en-4-ylmethanol esters and the 4(20), 5-diene by virtue of migration and elimination of the 5-O-ester moiety, thus providing useful methods for chemical modifications of the C-ring in taxinine derivatives.
- 公益社団法人日本薬学会の論文
- 1998-08-15
著者
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Hirota K
Gifu Pharmaceutical Univ. Gifu Jpn
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Hirota Kosaku
Gifu College Of Pharmacy
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SAKO Magoichi
Gifu Pharmaceutical University
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SUZUKI Hikokazu
Gifu Pharmaceutical University
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