Diastereoselective Synthesis of D- and L-myo-Inositol 3,4,5,6-Tetrakisphosphates from D-Glucose via Dihydroxylation of (+)-Conduritol B Derivatives
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概要
- 論文の詳細を見る
Syntheses of D- and L-myo-inositol 3, 4, 5, 6-tetrakisphosphates were achieved via diastereoselective 1,2-addition of vinylcopper reagent with the chiral aldehyde prepared from 1, 2, 5, 6-diisopropylidene-D-glucose, ring-closing metathesis of 1,7-diene with Grubbs catalyst followed by catalytic OsO_4 dihydroxylation of (+)-conduritol B derivatives.
- 公益社団法人日本薬学会の論文
- 2004-06-01
著者
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SHIMAZAWA Rumiko
Institute of Molecular & Cellular Biosciences, The University of Tokyo
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SHIRAI Ryuichi
Research and Education Center for Materials Science, Nara Institute of Science and Technology
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Shirai R
Research And Education Center For Materials Science Nara Institute Of Science And Technology
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Shimazawa Rumiko
Institute Of Molecular And Cellular Biosciences The University Of Tokyo
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SAITO Shintaro
Research and Education Center for Materials Science, Nara Institute of Science and Technology
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Saito Shintaro
Research And Education Center For Materials Science Nara Institute Of Science And Technology
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- Diastereoselective Synthesis of D- and L-myo-Inositol 3,4,5,6-Tetrakisphosphates from D-Glucose via Dihydroxylation of (+)-Conduritol B Derivatives