Phase Transformation Mechanisms in (AuCu)_<1-x>Pd_x Pseudobinary Alloys by Direct Aging Method

概要

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Phase transformation mechanisms in the AuCu-Pd pseudobinary system were studied by means of electrical resistivity measurements, hardness tests, X-ray diffraction and transmission electron microscopy. A direct aging method was employed to eliminate the otherwise unavoidable ordering that takes place rapidly during quenching into ice brine, hence it is important to distinguish the ordering processes with and without an incubation period. Three phase transformation modes occurred, namely; ordering at grain boundaries and in the grain interior with nucleation and growth mechanism after incubation, and spinodal ordering without any incubation period. The age-hardening of the alloys examined was attributed to AuCu I ordering. Nucleation and growth mechanism followed by twinning occurred in the specimens aged at higher temperatures, while spinodal ordering was seen in specimens aged in lower temperature. The spinodal ordering temperature of AuCu-Pd alloys increased according to Pd content.