水素化物発生/原子吸光法による河川水中のアンチモンの定量

概要

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Stibine, generated by mixing a 0.7 M sulfuric acid solution of antimony (III) with a 2% sodium tetrahydroborate solution in a mixing coil for 30 s, was separated from solution in a gas-liquid separator, and then swept into an electrically heated quartz furnace by manipulating electromagnetic relays and timers. Sharp peaks were recorded on a recorder. The detection limit (three times signal to noise ratio) for antimony (III) was 0.6 ng ml^<-1>. It took five minutes for one sample measurement. Interference from transition metals could eliminated by Chelex 100 separation. Antimony (V) was reduced by using a 0.1 M potassium iodide solution. The accuracy, checked with a biological standard reference material obtained from the National Institute of Standard and Technology (NIST) of USA, was within the certified value. Antimony in river water was determined by the present method.
社団法人日本分析化学会の論文
1996-11-05