Physical Methods for Treating the π-Electron Systems of Biopolymers such as Polypeptides and Polynucleotides in the Huckel Approximation
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概要
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Two simple physical methods are presented for calculating the electronic band structues of biopolymers such as hydrogen-bonded polypeptides or homopolynucleotides in the Huckel approximation. One is an extended LCAO MO method, or a method of Linear Combination of Molecular Orbitals, and the other is an extended Bloch wave method where the crystal orbitals are constructed from the molecular orbitals of elementary group with the aid of group theoretical considerations. The extended Bloch orbital method seems to be the most simple and powerful tool for dealing with the electronic structures of the multiple conjugate π-electron systems. The brief applications of these two methods to actual biopolymers are made only for the illustration.
- 社団法人日本物理学会の論文
- 1964-09-05
著者
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YOMOSA Sigeo
Department of Physics, Nagoya University
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Yomosa Sigeo
Department Of Physics University Of Tokyo
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Yomosa Sigeo
Department Of Physics Faculty Of Science Nagoya University
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