Theory of the Fe (II)⇆Fe (III) Transitions Induced by Cooperative Molecular Distortions in Molecular Crystals of Iron Compounds.II.Effects of the Variation of the Electron Number in a Molecule

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概要

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• A microscopic model is presented to provide a qualitative basis for understand-ing the Fe(II):Fe(III) transition accompanying molecular distortions inducedby the electron transfer in hemoproteins. The coupling of iron tons with theintramolecular distortions and the intermolecular coupling between the moleculardistortions are the driving force of the Fe(II):Fe(III) transitions in the presentmodel where the electron number of the system is varied as an external parameter.It is shown that the various types of the Fe(II):Fe(III) transitions such ascontinuous or discontinuous and with or without the molecular distortions mayoccur with changing the number of electrons.

• 社団法人日本物理学会の論文
• 1983-06-15

著者

• Kambara Takeshi

  Department Of Engineering Physics The University Of Electro-communications

• Sasaki Naoyuki

  Laboratory Of Physics Nippon Dental University

• Gondaira Kenichiro

  Department Of Engineering Physics The University Of Electro-communications

• OGATA Fumio

  Department of Engineering,Physics,The University of Electro-Communications

• Ogata Fumio

  Department Of Engineering Physics The University Of Electro-communications

• Kambara Takeshi

  Department Of Applied Physics And Chemistry University Of Electro-communications

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