Theory of Pressure-Induced Hugh-Spin⇆Low-Spin Transition in Compounds of Iron.II

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概要

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• The pressure-induced spin state transition in Fe(III) compounds are studiedon the basis of the ligand field theory by using the model in which the couplingsof Fe ion with a molecular distrotion and a lattice strain are taken into account.The calculated pressure dependences are classified into three patterns : (i) Thecontinuous and discontinuous transitions from the high-spin state (HS) to thelow-spin state (LS) with increasing pressure ; (ii) the continuous and discontinuoustransition from LS to JIS; (iii) the multiple transition LS-+HS-+LS-+HS. Thediscontinuous transitions are induced by the occurence or the disappearance ofthe cooperative intramolecular distortion.

• 社団法人日本物理学会の論文
• 1982-05-15

著者

• SASAKI Naoyuki

  Laboratory of Physics,Nippon Dental University

• Sasaki Naoyuki

  Laboratory Of Physics Nippon Dental University

• KAMBARA Takeshi

  Depertment of Engineering Physics,The University of Electro-Communications

• Kambara Takeshi

  Depertment Of Engineering Physics The University Of Electro-communications

関連論文

• Effect of the Gel-Liquid Crystal Transision on The Lipid-Preference of Protein in Lipid Bilayer Membranes
• MECHANISM OF LIPID LATERAL DIFFUSION IN LIPID BILAYER MEMBRANES
• Theory of Pressure-Induced Hugh-Spin⇆Low-Spin Transition in Compounds of Iron.II
• Theory of the Fe (II)⇆Fe (III) Transitions Induced by Cooperative Molecular Distortions in Molecular Crystals of Iron Compounds.II.Effects of the Variation of the Electron Number in a Molecule
• Theory of the Fe (II)⇆Fe (III) Transitions Induced by Cooperative Molecular Distortions in Molecular Crystals of Iron Compounds

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