The ENDOR Investigations of LiBaF_3: Min^<2+> Having the Inverse Perovskite Structure

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概要

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• The "F- and 'Li-rxoot measurements conclude that the Mn"' ion doped inLilac. crystal substitutes the Li" ton which is surrounded by a fluorine octa-hedron. The hyperfine (hf) interaction parameters of the ligand fluorine (Fl),second neishbour fluorine (F2) and lithium nuclei are obtained ; the unrairedspin fraction on 2s orbital of Fl is /.=O.61 '3 and that on 2p orbital. of Fl is .f, -/.=O.76 'A,. Usinn the Li and F2 hf rarameters the fractions /,(L.55'3) and /.(0.81 %) are separated by estimating the Fl-Li and Fl-F2 overlap integrals. The"Mn hf parameter is also obtained using ENDOR technique.

• 社団法人日本物理学会の論文
• 1980-07-15

著者

• Yosida Taturu

  Department Of Physics Nagoya University:low Temperature Center Osaka University

• Yosida Taturu

  Department Of Physics Faculty Of Science Osaka University:low Temperature Center Osaka University

• Yosida Taturu

  Low Teperature Center Osaka University

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• Electron Paramagnetic Resonance of Gd^ Centres in Several Perovskite Fluorides
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• The ENDOR Investigations of LiBaF_3: Min^ Having the Inverse Perovskite Structure
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