On the Intramolecular Light Scattering of the Non-Gaussian Chain
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概要
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The intramolecular light scattering function P(θ) of the non-Gaussian chain is investigated. For small values of s = (4π/λ) sin (θ/2), where λ is the wavelength of light in the solution, θ, the scattering angle, 1/P(θ) is given by 1 + (s^2/3)<γ_G^2>, and <γ_G^2> the mean square radius of gyration from the center of mass can be calculated according to various theories. For sufficiently large values of s, 1/P(θ) is expanded in terms of 1/s^2 so as to obtain the asymptotic behavior of 1/P(θ) vs. sin^2 (θ/2) plot. Excluded volume and swelling effects on 1/P(θ) are discussed in a general way. The asymptotic behavior for large s of the experimental results by Cantow-Schulz is analyzed according to the theory.
- 社団法人日本物理学会の論文
- 1960-05-05
著者
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Miyake Akira
Department Of Bioscience And Biotechnology Faculty Of Engineering Okayama University
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MIYAKE Akira
Department of Physics, Faculty of Liberal Arts and Science, Shizuoka University
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