溶融スラグ中へのアルミナ焼結体の溶解速度

概要

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The dissolution rate of alumina was calculated from the decreasing rate of radius of a cylindrical specimen dipped into CaO-SiO_2-Al_2O_3 (BF-type) or Na_2O-SiO_2 slags. The effects of revolution speed, temperature and slag composition on the dissolution rate were examined. The results are summarized as follows ; (1) The dissolution rate increased with increasing revolution speed. From this result, the dissolution rate was concluded to be limitted by mass transport in slag. (2) The apparent activation energies of mass transport in BF-type and soda-silicate slags were calculated to be 186 and 113 kJ・mol^<-1>, respectively. (3) From the EPMA analysis of specimen after experiment, it was observed that some slag penetrated into grain boundary of alumina specimen and a CaO・6Al_2O_3 compound was produced for CaO-SiO_2・Al_2O_3 slag, but that neither penetration layer nor compound are formed for soda-silicate slags.
社団法人日本鉄鋼協会の論文
1992-11-01