3A12 配向処理基板上に蒸着した液晶超薄膜の配向形成過程 : 表面SHG法と偏光紫外吸収分光法に基づく改良最大エントロピー法による解析(物理・物性)

概要

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We have investigated the molecular orientation formation of 5CB liquid crystalline films evaporated on a rubbed surface and a photoaligned surface composed of photoisomerizable alignment layer. The molecular orientational distributions evaluated by improved maximum entropy method, based on not only SHG results (3^<rd> order parameters) but also polarized UV absorption results (2^<nd> order parameters), show distinct difference between two treated surfaces ; the alignment axis of 5CB at rubbed surface begins to tilt up from the surface plane as the molecular density increases, while the alignment axis of 5CB at photoaligned surface remains on the surface plane eyen when the molecular density increases.
日本液晶学会の論文
2003-10-14