鋼中炭化物の電解分離法について : 鋼中非金属化合物に関する研究 I

概要

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The present paper deals with the technique for the electrolytic isolation of carbide from steel, without decomposition and contamination, by using the Koch-Sundermann method and others. The results obtained are as follows. (1) In order to dissolve all the matrix metal, the surface electric potential of steel must be set lower than the hydrogen potential. (2) In the case of dissolving in a partly passive state of steel surface, it is not desired to isolate the carbide at a too low current density. On the other hand if steel is dissolved in an active state, it need to isolate at a current density as low as possible. (3) The residues isolated electrolytically must be dried and weighed under the conditions of a high vacuum and a high temperature. (4) Copper or its compounds are contaminated in the residues isolated electrolytically from the low-alloy steel containing copper. (Cu content is 0.22%). When this copper included is separated from the residues by using KCN solution, part of carbide also tends to be decomposed. It is found that using the ammonium solution, this copper can be separated from the residue isolated eleotrolytically in 5% Na-citrate+1.2% KBr solution.
社団法人日本鉄鋼協会の論文
1962-10-01