赤外スペクトルによる[Co(en-d 4)_3]Cl_3・3T_2Oのβ放射線分解の研究
スポンサーリンク
概要
- 論文の詳細を見る
β-Radiolysis of [Co(en-d4)3]Cl3・3T2O was studied under a mild condition by means of infrared spectroscopy over a period of 8 months. The spectra became complex due to the appearance of many new bands in the initial process. This is explained in terms of the exchange reaction in hydrogen isotopes between water and ethylenediamine. It was found that ethylenediamine decomposed by ～50% in 100 days, forming ammonia coordinated to a Co2+ ion and an ammonium ion. On the other hand, a Co (Ⅲ) ammine complex, acetylene and so on were not found. A scheme for the β-radiolysis is proposed.
- 富山大学の論文
著者
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金坂 績
富山大学理学部
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金森 寛
Marine Biotechnology Institute
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金森 寛
富山大学理学部
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Kanamori K
Marine Biotechnology Institute
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西村 裕幸
富山大学理学部
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金森 寛[他]
富山大学理学部
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