Coordination and Photooxidation of Olefins with Ferric Ion
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概要
- 論文の詳細を見る
Coordination number (n) of stilbene to Fe^<3+> in acetonitrile has been shown to increase with the olefin concentration. The reciprocal plot of n vs. stilbene concentration is linear, which suggests that six molecules of stilbene may coordinate to Fe^<3+>. The photooxidation of aromatic olefins in the presence of Fe^<3+> and oxygen afford 80-90% yields of C-C cleavage products. Fe^<3+>-Sensitized photooxidation of styrene affords high yield of benzaldehyde whereas Cu^<2+> or 9,10-dicyanoanthracene without coordination gave poor yield of benzaldehyde..
- 鈴鹿工業高等専門学校の論文
- 2003-01-31
著者
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NAKAMURA TOMOYUKI
Department of Orthopedic Surgery, Graduate School of Medical Sciences, Kyushu University
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NAKAMURA Keishi
Department of Gastroenterologic Surgery, Division of Cancer Medicine, Graduate School of Medical Sci
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Katoh Makoto
Department of Biology and Pharmacology, Discovery Research Laboratory, Tanabe Seiyaku CO.LTD
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YOKOTA Masayuki
Department of Neurosurgery, Hyogo College of Medicine
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Katoh Makoto
Department Of Applied Chemistry Fuculty Of Engineering Naogya University
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Nakamura Tomoyuki
Department Of Applied Chemistry Fuculty Of Engineering Naogya University
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Nakamura Keishi
Department Of Chemistry And Biochemistry Suzuka National College Of Technology
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TOMIZAWA Kohtaro
Department of Chemistry and Biochemistry, Suzuka National College of Technology
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YONEDA Nao
Department of Chemistry and Biochemistry, Suzuka National College of Technology
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SAWAKI Yasuhiko
Department of Applied Chemistry, Fuculty of Engineering, Nagoya University
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Yoneda Nao
Department Of Chemistry And Biochemistry Suzuka National College Of Technology
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Sawaki Yasuhiko
Department Of Applied Chemistry Fuculty Of Engineering Nagoya University
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Sawaki Yasuhiko
Department Of Applied Chemistry Faculty Of Engineering Nagoya University
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Yokota Masayuki
Department Of Applied Chemistry Fuculty Of Engineering Nagoya University
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Tomizawa Kohtaro
Department Of Chemistry And Biochemistry Suzuka National College Of Technology
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冨澤 好太郎
Department of Chemistry and Biochemistry, Suzuka National College of Technology
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仲村 圭史
Department of Chemistry and Biochemistry, Suzuka National College of Technology
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米田 奈央
Department of Chemistry and Biochemistry, Suzuka National College of Technology
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