Aggregation of L-Cysteinato Tricobaltate(III) Anions by Lanthanide(III) Cations into Dimensional Structures That are Controlled by Diastereoisomerism and Ionic Size

スポンサーリンク

概要

• 論文の詳細を見る
• 2010-11-05

著者

• IGASHIRA KAMIYAMA

  Department of Chemistry, Graduate School of Science, Osaka University

• KONNO Takumi

  Department of Chemistry, Graduate School of Science, Osaka University

• Konno T

  Department Of Chemistry Graduate School Of Science Osaka University

• Konno T

  Department Of Chemistry Faculty Of Engineering Gunma University

• Konno Takumi

  Department Of Chemistry Graduate School Of Science Osaka University

• Igashira Kamiyama

  Department Of Chemistry Graduate School Of Science Osaka University

• Konno Takumi

  Dep. Of Chemistry Graduate School Of Sci. Osaka Univ.

• Konno Takumi

  Department Of Chemistry Faculty Of Engineering Gunma University

• YUAN Hou

  Department of Chemistry, Graduate School of Science, Osaka University

• Konno Takumi

  Department Of Chemsitry University Of Tsukuba

• Kawamoto Tatsuya

  Department Of Chemistry Faculty Of Science Kanagawa University

• Yuan Hou

  Department Of Chemistry Graduate School Of Science Osaka University

関連論文

• A S-bridged Co^Au^ICo^ Trinuclear Complex with L-Cysteinate Acting as a Flexible Dicarboxylate-type Metalloligand toward Manganese(II)
• Sulfur-Bridged Dinuclear and Tetranuclear Complexes Consisting of cis-[Ru(bpy)_2]^ and cis-[Ni(aet)_2] Units
• Sulfur-Bridged Heterotrimetallic Co^_2Pt^Ag^I Complexes Consisting of Two Tris(thiolato)-Type Cobalt(III) Octahedra Linked by Pt^ and Ag^I Ions
• Novel Aggregation of Bis(thiolato)-type Cobalt(III) Octahedra Assisted by Silver(I) Ions : Structural Interconversion by Counter Anions
• The First Ru^Pd^_2S_3 Metallochelate Ring Formed on a [Ru(bpy)_2]^ Core
• Sulfur-bridged Linkage of [Ni(thiolato)_2(amine)_2]-type Complexes with Linear Gold(I) Ions Assisted by Aurophilic Interaction
• A Remarkable Co^Mn^Ag^I Heterometallic Aggregate with L-Cysteinate That Accommodates Chiral Cobalt(III) Octahedra in a 1D Channel
• Alkylation of Nonbridging Thiolato Groups in an S-bridged Co^Pd^Co^ Trinuclear Complex : Control of Geometrical Isomerism by Tuning Trans Influence Due to Sulfur Donors
• A New Class of S-Bridged Co^MCo^ (M=Ni^, Pd^) Trinuclear Complexes with Mixed Aliphatic and Aromatic Thiolate Ligands : Synthesis, Characterization, and Stereochemistry
• Aggregation of Cobalt(III) Complexes with Single Thiolato or Selenolato Group Assisted by Ag^I Ion : Crystal Structure of Spontaneously Resolved 1D Coordination Polymers [Ag{Co(aet or aese)(en)_2}](NO_3)_3(aet=2-Aminoethanethiolate, aese=2-Aminoethanesele
• Stereoselective Preparation and Crystal Structures of ΔΛ-and ΔΔ-[Hg{Co(aet)_2(en)}_2]^ (aet = 2-Aminoethanethiolate): Conversion of a Racemic Co^Hg^ Dinuclear to an Optically Active Co^Hg^Co^ Trinuclear Structure
• First Aggregation of _L-Cysteinato Cobalt(III) Octahedrons Assisted by Trigonal-Planar Silver(I) and Trigonal-Prismatic Sodium(I) Ions
• Spontaneous Reduction of Gold(III) to Gold(I) That Leads to the Formation of S-Bridged Co^_2Au^I_2 Tetranuclear Structure Composed of Unprecedented C_1-cis(S)-[Co(aet)_2(en)]^+ Units : Synthesis and Characterization of C_2C_2- and C_1C_1-[Au_2{Co(aet
• Five-Coordinate Geometry of Cadmium(II) with Octahedral Bidentate-S,S Complex-Ligand cis(s)-[Co(aet)_2(en)]^+(aet=2-aminoethanethiolate) : Synthesis, Crystal Structures and Interconversion of S-Bridged Co^Cd^ Polynuclear Complexes
• Preparation and Properties of S-Bridged Co^III Ag^I_3Co^III Pentanuclear Complexes Having a Triple Helical Chirality. Crystal Structure of [Ag_3{Co(aet)_3}_2](BF_4)_3 (aet = 2-Aminoethanethiolate)
• Optically Active S-Bridged Co^Pd^ Polynuclear Complexes Derived from ΔΔ-[Ni{Co(aet)_2(R-pn)}_2]^ (aet=2-Aminoethanethiolate, R-pn=(R)-1,2-Propanediamine
• Synthesis, Crystal Structure, and Some Spectrochemical Properties of Optically Active S-Bridged Trinuclear Complex ΔΔ-[Ni{Co(aet)_2(R-pn)}_2]^ (aet=2-Aminoethanethiolate, R-pn=(R)-1,2-Propanediamine)
• Synthesis, Crystal Structures, and Some Properties of S-Bridged Pt(II)-M(III) (M=Co, Rh) Dinuclear Complexes with Square-Planar and Octahedral Geometries
• Stereoselectivity for S-Bridged Polynuclear Transition Metal Complexes Formed by Aggregation of Octahedral Complexes to Square-Planar Palladium(II)
• Preparation, Characterization, and Some Properties of Novel Dinuclear Complexes with a Coordinated Bridging Disulfide Bond. Crystal Structures of Δ_RΛ_S-[M_2(2-aminoethanethiolato)_4(cystamine)]^ (M = Ir^, Rh^)
• Synthesis, Crystal Structures, and Properties of S-Bridged Pt(II)-Ni(II) Dinuclear Complexes : Conversion of Square-Planar [Ni(aet)_2] to Octahedral Geometry by Forming an S-Bridged Structure with Pt(II) (aet=2-Aminoethanethiolate)
• Preparation, Stereochemistry, and Reactivity of Linear-Type S-Bridged MCr^M (M=Rh^,Ir^) Trinuclear Complexes with 2-Aminoethanethiolate (aet). Crystal Structures of Δ∧-[Cr{M(aet)_3}_2]^
• Syntheses and Some Properties of S-Bridged Pentanuclear Co(III)-Hg(II) or Rh(III)-Hg(II) Complexes with 2-Aminoethanethiolate. Crystal Structures of [{Rh(aet)_3}_2(HgCl_2)_3] and [{Rh(aet)_3}_2Hg_3(NO_3)_4](NO_3)_2
• Transfer of 2-Aminoethanethiolate (aet) from Nickel(II) to Cobalt(III) Coordination Sphere. Synsesis, Crystal Structure, and Some Properties of an S-Bridged Ttinuclear Complex [Ni{Co(aet)_2(en)}_2]^
• Aggregation of Cobalt(III) Complexes with Single Thiolato or Selenolato Group Assisted by Ag^I Ion : Crystal Structure of Spontaneously Resolved 1D Coordination Polymers [Ag{Co(aet or aese)(en)_2}](NO_3)_3(aet=2-Aminoethanethiolate, aese=2-Aminoethanesele
• Spontaneous Reduction of Gold(III) to Gold(I) That Leads to the Formation of S-Bridged Co^_2Au^I_2 Tetranuclear Structure Composed of Unprecedented C_1-cis(S)-[Co(aet)_2(en)]^+ Units : Synthesis and Characterization of C_2C_2- and C_1C_1-[Au_2{Co(aet
• Drastic Change in Dimensional Structures of D-Penicillaminato (Au^I_2Pt^_2Zn^)_n Coordination Polymers by Moderate Change in Solution pH
• A Novel Cis-Trans Isomerism Found in a Sulfur-bridged Pd^_2Au^I_2 Tetranuclear Complex with [Pd(amine)_2(thiolato)_2]-type Building Units
• Conversion of 2-Aminoethanethiolate (aet) to 2-Benzoylaminoethanethiolate (L) in a S-Bridged Diruthenium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units. Crystal Structures of ΔΔ/ΛΛ-[{Ru(bpy)_2}_2-(μ-Haet)_2]^ and ΔΔ/ΛΛ-[{Ru(bpy)_2}_2(μ-L)_2]^
• A New Class of S-Bridged Pentanuclear Complexes with a Triple Helical Chirality. Crystal Structure of [{Rh^(aet)_3}_2(Hg^Cl_2)_3](aet=2-aminoethanethiolate)
• First Geometrical Isomerization of[Co(D-pen-N, O, S)_2]^-Induced by Forming S-Bridged Structure with Au^I or Ag^I:Crystal Structure of a Co^_3Au^I_3 Hexanuclear Metallacycle[Au_3{Co(D-pen-N, O, S)_2}_3](D-pen=D-Penicillaminate)
• A S-Bridged Co^Cu^Co^ Trinuclear Complex with an Unusual Copper(II) Ion Bound by Four Aliphatic Thiolato Donors
• Reversible Conversion of Tetranuclear, Trinuclear, and Mononuclear Palladium(II) Complexes with D-Penicillaminate
• Mutual Chiral Discrimination between Tricationic and Trianionic Sulfur-bridge Tricobalt(III) Complexes
• A Novel S-bridged Pd^_2Hg^ Metallacycle of D-Penicillaminate that Forms a Unique Supramolecular Structure Combined with Tetraamminepalladium(II)
• Anion-controlled Preparation of Chiral S-Bridged Co^Pt^_2 and Co^_2Pt^_2 Complexes Consisting of [Co(D-penicillaminato-N,O,S)_2]^- and [Pt(CH_3NH_2)_2]^ Units
• The First S-Bridged Co^Cd^Co^ and Co^Cd^_2Co^ Structures Controlled by Chirality of Mono(thiolato)-Type Cobalt(III) Units
• First Conversion of a Square-planar [Ni(aet)_2] to an Octahederal [Ni(aet)_2L] by Forming S-Bridged Structure with Pt(II) (aet=2-Aminoethanethiolate: L = (H_2O)_2 or 2,2'-Bipyridine)
• Novel Aggregation of fac(S)-[Rh(aet)_3]by Square-Planar Palladium(II) : Crystal Structure of Spontaneously Resolved Rh^_3Pd^_2 Pentanuclear Complex [Pd{Pd(aet)}{Rh(aet)_2}{Rh(aet)_3}_2]Br_4(aet=2-Aminoethanethiolate)
• Sulfenato and Sulfinato Complex Formation via Oxidation of OC-6-3'2-Bis{2-[(2-pyridylmethyl)amino]ethanethiolato}cobalt(III)(1+) complex by Molecular Dioxygen
• The First Ligand Oxidation of Cobalt(III) Thiolato Complex by Molecular Dioxygen
• Novel Multinuclear Ni^Au^I_2 and Ni^Au^I_3 Complexes Containing D-Penicillaminate and Bis(diphenylphosphino)methane : Rational Expansion of 8-Membered to 12-Membered Chelating Metalloring
• A Novel Tridentate-N,N,S Iminothiolate Ligand That Leads to the Formation of S-Bridged Dinickel(II) and Tetracobalt(III) Structures
• Aggregation of Octahedral Thiolato Complexes by Forming Sulfur-Bridged Structures with Transition Metal Ions
• Enantioselective Aggregation of Cobalt(III) Octahedrons in a One-Dimensional S-Bridged Co^Ag^I Array That Leads to Spontaneous Resolution
• Chiral-Selective Formation of S-Bridged Co^Pd^Co^ Trinuclear Complexes by Using trans(N)-[Co(D-pen-N,O,S)_2]^- as a Bidentate-S,S Complexed-Ligand (D-pen=D-Penicillaminate
• A Novel Dinuclear Iridium(III) Complex with a Bridging Disulfide Bond. Conversion of Coordinated Thiolato to Coordinated Bridging Disulfide by Acid Oxidation
• Aggregation of L-Cysteinato Tricobaltate(III) Anions by Lanthanide(III) Cations into Dimensional Structures That are Controlled by Diastereoisomerism and Ionic Size
• Solid-state Thermal and Photochemical E/Z Isomerization of Bidentate-N,S Schiff Base Ligands in Iridium(III) Complexes
• A Pair of Trans and Cis Isomers of Platinum(II) Schiff Base Complex with N, S Chelate Containing Ferrocenyl Pendant Groups
• Valence lsomerization. Synthesis and Characterization of Cobalt and Nickel Complexes
• A Novel Octanuclear Copper(I) Complex with a Compressed Square Antiprismatic Cu_8 Core
• A Novel Trinuclear Platinum(II) Complex with C, N, S, Donor Ligands Containing Ferrocenyl Groups
• A Remarkable Enantioselectivity of Diastereomers of an L-Cysteinato Co^_3 Complex-anion toward a Racemic 2-Aminoethanethiolato Co^_2Ag^I_3 Complex-cation
• Three Types of Nickel(II) Complexes Derived from 2-Substituted Benzothiazoline ; Formation of a Tetranuclear Complex by a Sterically Induced Orthometallation Reaction
• Autonomous differentiation of Drosophila spermatogonia in vitro
• Preparation of Mixed-metal Polynuclear Complexes by Stepwise Phosphine-bridging Reaction
• Synthesis and Characterization of Nickel(II) Schiff Base Complexes with Methoxy or Methyl Groups at 2,6-Positions of the Pendant Phenyl Ring : the Control of cis and trans Geometries
• Concurrently Observed Activation of Aryl-oxygen and Alkyl-oxygen Bonds in The Formation of Rhodium(III) Complexes
• Synthesis, Structural Characterization, and Interconversion of S-Bridged Dinuclear and Hexanuclear Complexes Composed of cis(S)-[Co(aet)_2(en)]^+ and Trigonal-Bipyramidal Cadmium(II)(aet=2-Aminoethanethiolate, en=Ethylenediamine)
• Novel S-Bridged Tetranuclear Cobalt(III) Complexes with 2-Aminoethanethiolate Formed by Ligand Transfer from Nickel(II) to Cobalt(III)
• Synthesis and Properties of Linear-Type S-Bridged Rh^Ni^Rh^ Trinuclear Complexes with 2-Aminoethanethiolate (aet) or _L-Cysteinate (_L-cys). Crystal Structure of [Ni{Rh(aet)_3}_2](NO_3)_2
• Synthesis, Characterization, and Crystal Structures of Cis and Trans Isomers of a Platinate(II) Complex with D-Penicillaminate
• Halide-controlled Construction and Structural Determination of a Series of Thiolato-bridged 16-Nuclear Copper(I) Clusters from Benzothiazoline
• The formation and stereochemistry of [CoIII3(L-cys-N,S)n(aet)6-n]3-n type S-bridged complexes (n=0-6, L-cys=L-cysteinate, and aet=2-aminoethanethiolate).
• Synthesis and Structure of a Neutral Au^I_4Ni^_2 Hexanuclear Complex Containing D-Penicillaminate and 1,2-Bis(diphenylphosphino)ethane
• Thiolato-bridged Au^I_2Cu^I_2 and Cu^I_4 Metallorings Derived from Benzothiazoline : Can Gold(I) Plus Copper(I) Make Silver(I)?
• Preparation and some properties of bis(trimethylenediamine)cobalt(III) complexes with a bidentate-N,S or -N,Se ligand.
• S-bridged polynuclear complexes. I Selective formation and crystal structure of (+)6C0D0-bis(tris(L-cysteinato-N,S)cobaltate(III)-.MU.-S,.MU.-S',.MU.-S")cobalt(III) nitrate pentahydrate.
• タイトル無し
• Raman spectral characteristics of (Co(ida)n(dien)2-n)-type and related complexes.

もっと見る 閉じる

スポンサーリンク