Aggregation of Octahedral Thiolato Complexes by Forming Sulfur-Bridged Structures with Transition Metal Ions

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概要

• 論文の詳細を見る
• Chemical Society of Japanの論文
• 2004-04-15

著者

• KONNO Takumi

  Department of Chemistry, Graduate School of Science, Osaka University

• Konno T

  Department Of Chemistry Graduate School Of Science Osaka University

• Konno T

  Department Of Chemistry Faculty Of Engineering Gunma University

• Konno Takumi

  Dep. Of Chemistry Graduate School Of Sci. Osaka Univ.

• Konno Takumi

  Department Of Chemistry Faculty Of Engineering Gunma University

• Konno Takumi

  Department Of Chemsitry University Of Tsukuba

• Kawamoto Tatsuya

  Department Of Chemistry Faculty Of Science Kanagawa University

関連論文

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• Sulfur-Bridged Dinuclear and Tetranuclear Complexes Consisting of cis-[Ru(bpy)_2]^ and cis-[Ni(aet)_2] Units
• Sulfur-Bridged Heterotrimetallic Co^_2Pt^Ag^I Complexes Consisting of Two Tris(thiolato)-Type Cobalt(III) Octahedra Linked by Pt^ and Ag^I Ions
• Novel Aggregation of Bis(thiolato)-type Cobalt(III) Octahedra Assisted by Silver(I) Ions : Structural Interconversion by Counter Anions
• The First Ru^Pd^_2S_3 Metallochelate Ring Formed on a [Ru(bpy)_2]^ Core
• Sulfur-bridged Linkage of [Ni(thiolato)_2(amine)_2]-type Complexes with Linear Gold(I) Ions Assisted by Aurophilic Interaction
• A Remarkable Co^Mn^Ag^I Heterometallic Aggregate with L-Cysteinate That Accommodates Chiral Cobalt(III) Octahedra in a 1D Channel
• Alkylation of Nonbridging Thiolato Groups in an S-bridged Co^Pd^Co^ Trinuclear Complex : Control of Geometrical Isomerism by Tuning Trans Influence Due to Sulfur Donors
• A New Class of S-Bridged Co^MCo^ (M=Ni^, Pd^) Trinuclear Complexes with Mixed Aliphatic and Aromatic Thiolate Ligands : Synthesis, Characterization, and Stereochemistry
• Aggregation of Cobalt(III) Complexes with Single Thiolato or Selenolato Group Assisted by Ag^I Ion : Crystal Structure of Spontaneously Resolved 1D Coordination Polymers [Ag{Co(aet or aese)(en)_2}](NO_3)_3(aet=2-Aminoethanethiolate, aese=2-Aminoethanesele
• Stereoselective Preparation and Crystal Structures of ΔΛ-and ΔΔ-[Hg{Co(aet)_2(en)}_2]^ (aet = 2-Aminoethanethiolate): Conversion of a Racemic Co^Hg^ Dinuclear to an Optically Active Co^Hg^Co^ Trinuclear Structure
• First Aggregation of _L-Cysteinato Cobalt(III) Octahedrons Assisted by Trigonal-Planar Silver(I) and Trigonal-Prismatic Sodium(I) Ions
• Spontaneous Reduction of Gold(III) to Gold(I) That Leads to the Formation of S-Bridged Co^_2Au^I_2 Tetranuclear Structure Composed of Unprecedented C_1-cis(S)-[Co(aet)_2(en)]^+ Units : Synthesis and Characterization of C_2C_2- and C_1C_1-[Au_2{Co(aet
• Five-Coordinate Geometry of Cadmium(II) with Octahedral Bidentate-S,S Complex-Ligand cis(s)-[Co(aet)_2(en)]^+(aet=2-aminoethanethiolate) : Synthesis, Crystal Structures and Interconversion of S-Bridged Co^Cd^ Polynuclear Complexes
• Preparation and Properties of S-Bridged Co^III Ag^I_3Co^III Pentanuclear Complexes Having a Triple Helical Chirality. Crystal Structure of [Ag_3{Co(aet)_3}_2](BF_4)_3 (aet = 2-Aminoethanethiolate)
• Optically Active S-Bridged Co^Pd^ Polynuclear Complexes Derived from ΔΔ-[Ni{Co(aet)_2(R-pn)}_2]^ (aet=2-Aminoethanethiolate, R-pn=(R)-1,2-Propanediamine
• Synthesis, Crystal Structure, and Some Spectrochemical Properties of Optically Active S-Bridged Trinuclear Complex ΔΔ-[Ni{Co(aet)_2(R-pn)}_2]^ (aet=2-Aminoethanethiolate, R-pn=(R)-1,2-Propanediamine)
• Synthesis, Crystal Structures, and Some Properties of S-Bridged Pt(II)-M(III) (M=Co, Rh) Dinuclear Complexes with Square-Planar and Octahedral Geometries
• Stereoselectivity for S-Bridged Polynuclear Transition Metal Complexes Formed by Aggregation of Octahedral Complexes to Square-Planar Palladium(II)
• Preparation, Characterization, and Some Properties of Novel Dinuclear Complexes with a Coordinated Bridging Disulfide Bond. Crystal Structures of Δ_RΛ_S-[M_2(2-aminoethanethiolato)_4(cystamine)]^ (M = Ir^, Rh^)
• Synthesis, Crystal Structures, and Properties of S-Bridged Pt(II)-Ni(II) Dinuclear Complexes : Conversion of Square-Planar [Ni(aet)_2] to Octahedral Geometry by Forming an S-Bridged Structure with Pt(II) (aet=2-Aminoethanethiolate)
• Preparation, Stereochemistry, and Reactivity of Linear-Type S-Bridged MCr^M (M=Rh^,Ir^) Trinuclear Complexes with 2-Aminoethanethiolate (aet). Crystal Structures of Δ∧-[Cr{M(aet)_3}_2]^
• Syntheses and Some Properties of S-Bridged Pentanuclear Co(III)-Hg(II) or Rh(III)-Hg(II) Complexes with 2-Aminoethanethiolate. Crystal Structures of [{Rh(aet)_3}_2(HgCl_2)_3] and [{Rh(aet)_3}_2Hg_3(NO_3)_4](NO_3)_2
• Transfer of 2-Aminoethanethiolate (aet) from Nickel(II) to Cobalt(III) Coordination Sphere. Synsesis, Crystal Structure, and Some Properties of an S-Bridged Ttinuclear Complex [Ni{Co(aet)_2(en)}_2]^
• Aggregation of Cobalt(III) Complexes with Single Thiolato or Selenolato Group Assisted by Ag^I Ion : Crystal Structure of Spontaneously Resolved 1D Coordination Polymers [Ag{Co(aet or aese)(en)_2}](NO_3)_3(aet=2-Aminoethanethiolate, aese=2-Aminoethanesele
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• Drastic Change in Dimensional Structures of D-Penicillaminato (Au^I_2Pt^_2Zn^)_n Coordination Polymers by Moderate Change in Solution pH
• A Novel Cis-Trans Isomerism Found in a Sulfur-bridged Pd^_2Au^I_2 Tetranuclear Complex with [Pd(amine)_2(thiolato)_2]-type Building Units
• Conversion of 2-Aminoethanethiolate (aet) to 2-Benzoylaminoethanethiolate (L) in a S-Bridged Diruthenium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units. Crystal Structures of ΔΔ/ΛΛ-[{Ru(bpy)_2}_2-(μ-Haet)_2]^ and ΔΔ/ΛΛ-[{Ru(bpy)_2}_2(μ-L)_2]^
• A New Class of S-Bridged Pentanuclear Complexes with a Triple Helical Chirality. Crystal Structure of [{Rh^(aet)_3}_2(Hg^Cl_2)_3](aet=2-aminoethanethiolate)
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• Chiral-Selective Formation of S-Bridged Co^Pd^Co^ Trinuclear Complexes by Using trans(N)-[Co(D-pen-N,O,S)_2]^- as a Bidentate-S,S Complexed-Ligand (D-pen=D-Penicillaminate
• A Novel Dinuclear Iridium(III) Complex with a Bridging Disulfide Bond. Conversion of Coordinated Thiolato to Coordinated Bridging Disulfide by Acid Oxidation
• Aggregation of L-Cysteinato Tricobaltate(III) Anions by Lanthanide(III) Cations into Dimensional Structures That are Controlled by Diastereoisomerism and Ionic Size
• Solid-state Thermal and Photochemical E/Z Isomerization of Bidentate-N,S Schiff Base Ligands in Iridium(III) Complexes
• A Pair of Trans and Cis Isomers of Platinum(II) Schiff Base Complex with N, S Chelate Containing Ferrocenyl Pendant Groups
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• A Novel Octanuclear Copper(I) Complex with a Compressed Square Antiprismatic Cu_8 Core
• A Novel Trinuclear Platinum(II) Complex with C, N, S, Donor Ligands Containing Ferrocenyl Groups
• A Remarkable Enantioselectivity of Diastereomers of an L-Cysteinato Co^_3 Complex-anion toward a Racemic 2-Aminoethanethiolato Co^_2Ag^I_3 Complex-cation
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• Concurrently Observed Activation of Aryl-oxygen and Alkyl-oxygen Bonds in The Formation of Rhodium(III) Complexes
• Synthesis, Structural Characterization, and Interconversion of S-Bridged Dinuclear and Hexanuclear Complexes Composed of cis(S)-[Co(aet)_2(en)]^+ and Trigonal-Bipyramidal Cadmium(II)(aet=2-Aminoethanethiolate, en=Ethylenediamine)
• Novel S-Bridged Tetranuclear Cobalt(III) Complexes with 2-Aminoethanethiolate Formed by Ligand Transfer from Nickel(II) to Cobalt(III)
• Synthesis and Properties of Linear-Type S-Bridged Rh^Ni^Rh^ Trinuclear Complexes with 2-Aminoethanethiolate (aet) or _L-Cysteinate (_L-cys). Crystal Structure of [Ni{Rh(aet)_3}_2](NO_3)_2
• Synthesis, Characterization, and Crystal Structures of Cis and Trans Isomers of a Platinate(II) Complex with D-Penicillaminate
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• Synthesis and Structure of a Neutral Au^I_4Ni^_2 Hexanuclear Complex Containing D-Penicillaminate and 1,2-Bis(diphenylphosphino)ethane
• Thiolato-bridged Au^I_2Cu^I_2 and Cu^I_4 Metallorings Derived from Benzothiazoline : Can Gold(I) Plus Copper(I) Make Silver(I)?
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• Raman spectral characteristics of (Co(ida)n(dien)2-n)-type and related complexes.

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