Preparation of Mixed-metal Polynuclear Complexes by Stepwise Phosphine-bridging Reaction
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概要
- 論文の詳細を見る
- 2004-10-05
著者
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Kawamoto Tatsuya
Department Of Chemistry Faculty Of Science Kanagawa University
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Kawamoto Tatsuya
Department Of Chemistry Graduate School Of Science Osaka University
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Aizawa Sen-ichi
Faculty Of Engineering Toyama University
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SAITO Kenji
Faculty of Engineering, Toyama University
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Saito Kenji
Faculty Of Engineering Toyama University
関連論文
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- Sulfur-Bridged Dinuclear and Tetranuclear Complexes Consisting of cis-[Ru(bpy)_2]^ and cis-[Ni(aet)_2] Units
- Sulfur-Bridged Heterotrimetallic Co^_2Pt^Ag^I Complexes Consisting of Two Tris(thiolato)-Type Cobalt(III) Octahedra Linked by Pt^ and Ag^I Ions
- Novel Aggregation of Bis(thiolato)-type Cobalt(III) Octahedra Assisted by Silver(I) Ions : Structural Interconversion by Counter Anions
- The First Ru^Pd^_2S_3 Metallochelate Ring Formed on a [Ru(bpy)_2]^ Core
- Sulfur-bridged Linkage of [Ni(thiolato)_2(amine)_2]-type Complexes with Linear Gold(I) Ions Assisted by Aurophilic Interaction
- A Remarkable Co^Mn^Ag^I Heterometallic Aggregate with L-Cysteinate That Accommodates Chiral Cobalt(III) Octahedra in a 1D Channel
- Alkylation of Nonbridging Thiolato Groups in an S-bridged Co^Pd^Co^ Trinuclear Complex : Control of Geometrical Isomerism by Tuning Trans Influence Due to Sulfur Donors
- A New Class of S-Bridged Co^MCo^ (M=Ni^, Pd^) Trinuclear Complexes with Mixed Aliphatic and Aromatic Thiolate Ligands : Synthesis, Characterization, and Stereochemistry
- Aggregation of Cobalt(III) Complexes with Single Thiolato or Selenolato Group Assisted by Ag^I Ion : Crystal Structure of Spontaneously Resolved 1D Coordination Polymers [Ag{Co(aet or aese)(en)_2}](NO_3)_3(aet=2-Aminoethanethiolate, aese=2-Aminoethanesele
- Stereoselective Preparation and Crystal Structures of ΔΛ-and ΔΔ-[Hg{Co(aet)_2(en)}_2]^ (aet = 2-Aminoethanethiolate): Conversion of a Racemic Co^Hg^ Dinuclear to an Optically Active Co^Hg^Co^ Trinuclear Structure
- First Aggregation of _L-Cysteinato Cobalt(III) Octahedrons Assisted by Trigonal-Planar Silver(I) and Trigonal-Prismatic Sodium(I) Ions
- Spontaneous Reduction of Gold(III) to Gold(I) That Leads to the Formation of S-Bridged Co^_2Au^I_2 Tetranuclear Structure Composed of Unprecedented C_1-cis(S)-[Co(aet)_2(en)]^+ Units : Synthesis and Characterization of C_2C_2- and C_1C_1-[Au_2{Co(aet
- Five-Coordinate Geometry of Cadmium(II) with Octahedral Bidentate-S,S Complex-Ligand cis(s)-[Co(aet)_2(en)]^+(aet=2-aminoethanethiolate) : Synthesis, Crystal Structures and Interconversion of S-Bridged Co^Cd^ Polynuclear Complexes
- Drastic Change in Dimensional Structures of D-Penicillaminato (Au^I_2Pt^_2Zn^)_n Coordination Polymers by Moderate Change in Solution pH
- A Novel Cis-Trans Isomerism Found in a Sulfur-bridged Pd^_2Au^I_2 Tetranuclear Complex with [Pd(amine)_2(thiolato)_2]-type Building Units
- Conversion of 2-Aminoethanethiolate (aet) to 2-Benzoylaminoethanethiolate (L) in a S-Bridged Diruthenium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units. Crystal Structures of ΔΔ/ΛΛ-[{Ru(bpy)_2}_2-(μ-Haet)_2]^ and ΔΔ/ΛΛ-[{Ru(bpy)_2}_2(μ-L)_2]^
- A S-Bridged Co^Cu^Co^ Trinuclear Complex with an Unusual Copper(II) Ion Bound by Four Aliphatic Thiolato Donors
- Reversible Conversion of Tetranuclear, Trinuclear, and Mononuclear Palladium(II) Complexes with D-Penicillaminate
- Mutual Chiral Discrimination between Tricationic and Trianionic Sulfur-bridge Tricobalt(III) Complexes
- A Novel S-bridged Pd^_2Hg^ Metallacycle of D-Penicillaminate that Forms a Unique Supramolecular Structure Combined with Tetraamminepalladium(II)
- Anion-controlled Preparation of Chiral S-Bridged Co^Pt^_2 and Co^_2Pt^_2 Complexes Consisting of [Co(D-penicillaminato-N,O,S)_2]^- and [Pt(CH_3NH_2)_2]^ Units
- The First S-Bridged Co^Cd^Co^ and Co^Cd^_2Co^ Structures Controlled by Chirality of Mono(thiolato)-Type Cobalt(III) Units
- Sulfenato and Sulfinato Complex Formation via Oxidation of OC-6-3'2-Bis{2-[(2-pyridylmethyl)amino]ethanethiolato}cobalt(III)(1+) complex by Molecular Dioxygen
- The First Ligand Oxidation of Cobalt(III) Thiolato Complex by Molecular Dioxygen
- Aggregation of Octahedral Thiolato Complexes by Forming Sulfur-Bridged Structures with Transition Metal Ions
- Thiolato-Ligand Substitution Reaction with Halide Ions of Five-Coordinate Trigonal-Bipyramidal Palladium(II) Complexes with Tris(2-(diphenylphosphino)ethyl)phosphine. Electronic and Steric Effects on the Reaction Mechanism
- Circular Dichroism Spectrophotometric Determination of Metal Ions Using Optically Active Tris(tiolato) Type Rhodium(III) Complexes
- Circular Dichroism Spectrophotometric Determination of Metal Ions by Using Optically Resolved Sparingly Soluble fac (S)-[Rh (aet) _3] (aet = 2-Aminoethanethiolate)
- Aggregation of L-Cysteinato Tricobaltate(III) Anions by Lanthanide(III) Cations into Dimensional Structures That are Controlled by Diastereoisomerism and Ionic Size
- Solid-state Thermal and Photochemical E/Z Isomerization of Bidentate-N,S Schiff Base Ligands in Iridium(III) Complexes
- A Pair of Trans and Cis Isomers of Platinum(II) Schiff Base Complex with N, S Chelate Containing Ferrocenyl Pendant Groups
- Valence lsomerization. Synthesis and Characterization of Cobalt and Nickel Complexes
- A Novel Octanuclear Copper(I) Complex with a Compressed Square Antiprismatic Cu_8 Core
- A Novel Trinuclear Platinum(II) Complex with C, N, S, Donor Ligands Containing Ferrocenyl Groups
- A Remarkable Enantioselectivity of Diastereomers of an L-Cysteinato Co^_3 Complex-anion toward a Racemic 2-Aminoethanethiolato Co^_2Ag^I_3 Complex-cation
- Kinetic Effect of Zinc(II) and Cadmium(II) Ions on Configurational Inversion of Δ_-fac(S)-Tris(L-Cysteinato-N, S)cobalt(III) Complex
- Discrimination of Thiolate Group in L-Cysteinate and Glutathionate by Axial Coordination Site of Five-Coordinate Trigonal-Bipyramidal Palladium(II) Complex with Tris(2-(diphenylphosphino)ethyl)phosphine
- Three Types of Nickel(II) Complexes Derived from 2-Substituted Benzothiazoline ; Formation of a Tetranuclear Complex by a Sterically Induced Orthometallation Reaction
- Autonomous differentiation of Drosophila spermatogonia in vitro
- Rapid Equilibrium between Trigonal-bipyramidal and Square-pyramidal Geometries of 1-Popanethiolato Platinum(II) Complex with Tris[2-(diphenylphosphino)ethyl]phosphine
- Preparation of Mixed-metal Polynuclear Complexes by Stepwise Phosphine-bridging Reaction
- Synthesis and Characterization of Nickel(II) Schiff Base Complexes with Methoxy or Methyl Groups at 2,6-Positions of the Pendant Phenyl Ring : the Control of cis and trans Geometries
- Concurrently Observed Activation of Aryl-oxygen and Alkyl-oxygen Bonds in The Formation of Rhodium(III) Complexes
- Synthesis, Characterization, and Crystal Structures of Cis and Trans Isomers of a Platinate(II) Complex with D-Penicillaminate
- Halide-controlled Construction and Structural Determination of a Series of Thiolato-bridged 16-Nuclear Copper(I) Clusters from Benzothiazoline
- Synthesis and Structure of a Neutral Au^I_4Ni^_2 Hexanuclear Complex Containing D-Penicillaminate and 1,2-Bis(diphenylphosphino)ethane
- Thiolato-bridged Au^I_2Cu^I_2 and Cu^I_4 Metallorings Derived from Benzothiazoline : Can Gold(I) Plus Copper(I) Make Silver(I)?
- Raman spectral characteristics of (Co(ida)n(dien)2-n)-type and related complexes.