Inclusion of Alkali Metal Ions by Permethylated Inulin Studied by Electrospray Ionization Mass and Multinuclear Nuclear Magnetic Resonance Spectrometric Approaches

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概要

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• Inclusions of alkali metal ions by permethylated inulin (MeInu) were examined by electrospray ionization (ESI) mass spectrometry and multinuclear nuclear magnetic resonance (NMR) spectroscopy. Complexes of MeInu with metal ions were observed as multicharged ions in ESI mass spectra. The number of fructofuranose units of MeInu binding to one metal ion was 12, 6, and 7 for Li+, K+, and Cs+, respectively, on the basis of ESI mass spectra. However, the number estimated on the basis of multinuclear NMR spectra was 2 and 3-4 for Li+ and K+, respectively. The binding ability of MeInu to Li+ is very weak, so metal ions dissociate from the complex in the ionization process. As a result, the ratio of fructofuranose units to Li+ ions might have been estimated in excess. In the case of K+ and Cs+, the number of fructofuranose units binding a metal ion is found to be in good agreement with that of the oxyethylene units of crown ethers in solution.

• 日本質量分析学会の論文
• 2009-02-01

著者

• Iwahori Yukimasa

  Department Of Applied Chemistry Kansai University Suita

• Tanaka Juichi

  Department of Orthopaedic Surgery, Hyogo College of Medicine

• ARAKAWA Ryuichi

  Department of Applied Chemistry, Faculty of Chemistry, Materials and Bioengineering, Kansai Universi

• Shizuma Motohiro

  Technochemistry Osaka Municipal Technical Research Institute

• SHIZUMA Motohiro

  Department of Biochemistry, Osaka Municipal Technical Research Institute

• TAKAI Yoshio

  Materials Analysis Center, The Institute of Scientific and Industrial Research, Osaka University

• Takeda Yuka

  Department Of Applied Chemistry & Biochemistry Faculty Of Engineering Kumamoto University

• Takai Y

  Materials Analysis Center The Institute Of Scientific And Industrial Research Osaka University

• Takai Y

  The Institute Of Scientific And Industrial Research Osaka University

• Takai Yoshio

  Materials Analysis Center The Institute Of Scientific And Industrial Research Osaka University

• Sawada M

  Materials Analysis Center The Institute Of Scientific And Industrial Research Osaka University

• Sawada Masami

  Materials Analysis Center The Institute Of Scientific And Industrial Research Osaka University

• Tanaka Juichi

  Department Of Applied Chemistry Osaka Institute Of Technology

• YAMADA Hitoshi

  Materials Analysis Center, The Institute of Scientific and Industrial Research, Osaka University

• GOSHIMA Gakuto

  Department of Applied Chemistry, Osaka Institute of Technology

• Goshima Gakuto

  Department Of Applied Chemistry Osaka Institute Of Technology

• Shizuma Motohiro

  Department Of Biochemistry Osaka Municipal Technical Research Institute

• Yamada Hidetoshi

  Materials Analysis Center The Institute Of Scientific And Industrial Research Osaka University

• Arakawa R

  Department Of Applied Chemistry Kansai University

• Arakawa Ryuichi

  Department Of Applied Chemistry Faculty Of Engineering Kansai University

• Takai Y

  Toyama Univ. Toyama

• Takai Yoshio

  Material Analysis Center, The Institute of Scientific and Industrial Research, Osaka University

• SAWADA Masami

  Material Analysis Center, The Institute of Scientific and Industrial Research, Osaka University

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