メソポーラスシリカの均一内部修飾反応と, その重合場としての応用

元データ 2008-12-01 社団法人 有機合成化学協会

概要

Preparation, surface modification of mesoporous silica, and its application to the polymer synthesis were reviewed. The template synthesis of mesoporous materials by using surfactants and block copolym ers were first introduced. The surface modication within the mesoporous interiorwas classified into two type reactions: Cocondensation of tetraalkoxysilane with functional molecules having silane coupling parts. The Grignard reagent-utilized functionalization of mesoporous material was also introduced with the analysis of the functionalization efficiency by IR spectroscopy. The application of the functionalized mesoporous materials to the polymer synthesis, especially controlled synthesis, was introduced.

著者

野村 淳子 東京工業大学資源化学研究所
芝崎 祐二 岩手大学工学部応用化学科

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