Synthesis of Optically Active Vomifoliol and Roseoside Stereoisomers
スポンサーリンク
概要
- 論文の詳細を見る
A synthesis of optically active vomifoliol stereoisomers 1-4 and their glucosides, roseoside stereoisomers 5-8, was accomplished via α-acetylenic alcohol 11a or 11b effectively prepared by an asymmetric transfer hydrogenation of α, β-acetylenic ketone 10. Simultaneous separation of these stereoisomers by HPLC was also perfomed.
- 公益社団法人日本薬学会の論文
- 2005-05-01
著者
-
ITO Masayoshi
Kobe Pharmaceutical University
-
Yamano Yumiko
Kobe Pharmaceutical University
-
Yamano Yumiko
Kobe College Pharm.
-
Ito Masayoshi
Kobe College Pharm.
-
Yamano Yumiko
Dep. Of Organic Chemistry For Life Sci. Kobe Pharmaceutical Univ.
関連論文
- Retinoids and Related Compounds. Part 22. Synthesis of β-Ionone Analog Tricarbonyliron Complexes
- FLUORESCENCE PROPERTIES OF PHOTOSYNTHETIC ANTENNA PIGMENTS, KETOCAROTENOIDS.
- First Total Synthesis of Cucurbitaxanthin A Applying Regioselective Ring Opening of Tetrasubstituted Epoxides
- Total Synthesis of Capsanthin Using Lewis Acid-Promoted Regio- and Stereoselective Rearrangement of Tetrasubstituted Epoxide
- Isolation of 9Z β-Carotene from Dunaliella bardawil and Its Stereoselective Synthesis
- Stereoselective Synthesis of Optically Active 3-Hydroxy-7,8-dihydro-β-ionol-glucosides
- First Total Synthesis of Mytiloxanthin
- Identification of (3S, 9R)- and (3S, 9S)-Megastigma-6,7-dien-3,5,9-triol 9-O-β-D-glucopyranosides as Damascenone Progenitors in the Flowers of Rosa damascena Mill.(Food & Nutrition Science)
- Stereocontrolled Synthesis of Optically Active β-D-Glucopyranosides of 3-Hydroxy-7,8-didehydro-β-ionol
- Synthesis of Optically Active Vomifoliol and Roseoside Stereoisomers
- An Improved Synthesis of Benzocycloalkanone Derivatives
- Synthesis of 9Z-9-Substituted Retinoic Acids by Palladium Catalyzed Coupling Reaction of a Vinyl Triflate with Alkenyl Stannanes
- Retinoids and Related Compounds. Part 12. Optical Resolution of(.+-.)-All-trans-3-Hydroxyretinal by Use of High-Performance Liquid Chromatography.
- High-Performance Liquid Chromatographic Separation and Spectral Identification of the Photoreaction Products of Methyl 5,8-Epoxyretinoate.