Stereoselective Synthesis via Palladium-Catalyzed Intramolecular Bis-Silylation
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概要
- 論文の詳細を見る
Stereoselective intramolecular bis-silylation reactions catalyzed by isonitrile-palladium (O) complexes are described. Their useful synthetic applications were demonstrated by stereoselective asymmetric synthesis of a natural product and building blocks, e.g., (-) -avenaciolide was synthesized from (R) -3-vinyl-1-undecen-4-ol, and highly enantio-enriched allylsilanes and allenylsilanes were synthesized from the corresponding optically active allylic and propargylic alcohols, respectively. Attempts at catalytic intramolecular asymmetric bis-silylation with optically active t-alkyl isocyanide complexes are also described.
- 社団法人 有機合成化学協会の論文
- 1997-11-01
著者
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Ito Yoshihiko
Department of Molecular Science and Technology, Doshisha University
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SUGINOME Michinori
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto Un
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Suginome Michinori
Department Of Synthetic Chemistry And Biological Chemistry Graduate School Of Engineering Kyoto Univ
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Suginome Michinori
Department Of Synthetic Chemistry And Biological Chemistry Faculty Of Engineering Kyoto University
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Ito Yoshihiko
Department Of Mathematics Faculty Of Education Kumamoto University
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Ito Yoshihiko
Department Of Synthetic Chemistry And Biological Chemistry Graduate School Of Engineering Kyoto Univ
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