Rhodium(I)-Catalyzed Acylation of Alkyne with Acylsilane: Transformation of 5- or 6-Alkynoylsilane to α-Alkylidenecycloalkanone

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概要

• 論文の詳細を見る
• 2001-12-05

著者

• NARASAKA Koichi

  Department of Chemistry, School of Science, The University of Tokyo

• YAMANE Motoki

  Department of Chemistry, Graduate School of Science, The University of Tokyo

• Yamane Motoki

  Department Of Chemistry Graduate School Of Science The University Of Tokyo

• AMEMIYA Takuma

  Department of Chemistry, Graduate School of Science, The University of Tokyo

• Narasaka Koichi

  Department Of Applied Chemistry Faculty Of Engineering Kyushu Institute Of Technology

• Amemiya T

  Yokohama National Univ. Yokohama

• Narasaka Koichi

  Department of Chemistry, Graduate School of Science, The University of Tokyo

関連論文

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• Regioselectivesynthesis of 8-Hydroxytetrahydroquinolines by the Cyclization of m-Hydroxyphenethyl Ketone O-2, 4-Dinitrophenyloximes
• Radical Cyclization of O-Pentafluorobenzoyloximes Having a (Cyclohexadiene)Fe(CO)_3 Moiety
• Transfomation of Oximes of Phenethy Ketone Derivatives to Quinolines and Azaspirotrienones Catalyzed by Tetrabutylammonium Perrhenate and Trifluoromethanesulfonic Acid
• Synthesis of Azaspirodienones via Intramolecular Cyclization of p-Hydroxybenzylacetone Oximes and Their Transformation into Quinolines
• Beckmann Rearrangement of Oximes Catalyzed with Tetrabutylammonium Perrhenate and ATrifluoromethanesulfonic Acid
• Synthesis of Quinolines via Intramolecular Cyclization of Benzylacetone Oxime Derivatives Catalyzed with Tetrabutylammonium Perrhenate(VII) and Trifluoromethanesulfonic Acid
• Beckmann Rearrangement Catalyzed by the Combined Use of Tetrabutylammonium Perrhenate(VII) and Trifluoromethanesulfonic Acid
• Synthesis of Terphenylboronic Acid Derivatives and Recognition of Anomers of 2-Deoxyribofuranoside
• Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(pyridine-2-carboxylate) and Its Application to Total Synthesis of 10-Isothiocyanatoguaia-6-ene
• Total Synthesis of 10-Isothiocyanatoguaia-6-ene
• Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(2-pyridinecarboxylate)
• Lewis Acid-Promoted Disproportionation Reaction of Aromatic Vinyl Ethers and Acetals and Its Application to the Synthesis of Paracotoin
• Photochemical Generation of Radical Species from α - Stannyl Ethers and Their Reaction with Conjugate Enones
• Synthesis of α-Carbolines from β-(3-Indolyl) Ketone O-2,4-Dinitrophenyloximes
• Substituent Effect of 1,4-Benzenedicarbonitriles as Sensitizers on the Photoinduced Electron Transfer Reactions in Alcohol
• Intramolecular Substitution Reaction of Lithium Alkylidene Carbenoids. Regioselective Synthesis of Indenes
• Palladium-Catalyzed Carboacylation of Alkenes by Using Acylchromates as Acyl Donors
• Palladium-Catalyzed Synthesis of α-Diketones from Acylchromates, Indoarenes, and Carbon Monoxide
• Palladium Catalyzed Coupling Reaction of Acylchromate Complexed and Allylic Bromides
• A Novel Rearrangement of Chromium Allyloxy(aryl) carbene Complexes Catalyzed by Pd(0)
• Generation of a Cation Radical from 2-Pivaloyl-1-tributylstannyl-1,2,3,4-tetrahydroisoquinoline and the Reaction with Carbon Nucleophiles
• Synthesis of (±)-Stemonamide by the Application of Oxidative Coupling Reactions of Stannyl Compounds with Silyl Enol Ethers
• Oxidative Generation of α-Radicals of Carbonyl Compounds from the α-Stannyl Derivatives and Their Reactions with Electron-Rich Olefins
• Generation of α-Radicals of Acetic Acid Derivatives from α-Stannyl Ester and Amide and Their Reactions with Electron-Rich Olefins
• Synthesis of Dihydropyrroles by the Intramolecular Addition of Alkylideneaminyl Radicals Generated from 0-2, 4-Dinitrophenyloximes of γ, δ-Unsaturated Ketones
• Synthesis of Dihydropyrroles and Tetrahydropyridines by the Intramolecular Cyclization of O-Methylsulfonyloximes Having an Active Methine Group
• Regioselective Acylation of (5-Alkylidene-1, 3-cyciohexadiene)tricarbonyliron Complexes by the Reaction with Organometallic Reagents
• Preparation of M-Acylaniline Derivatives by the Reaction of Tricarbonyl(cyclohexadienone O-benzyloxime)iron Complex and Higher Order Cuprates
• Asymmetric Total Synthesis of Epolactaene
• S_N2 Substitution on sp^2 Nitrogen of Protonated Oxime
• Bissilyl Ketone ; A Convenient Method for the Synthesis and Its Pd(0)Catalyzed Reaction with Alkenes and Alkynes
• Generation of Radical Species From Cyclohexane-1,2-dione and the Reaction with Olefins : Preparation of 4,5-Dihydro-7 ( 6H ) -benzofuranone Derivatives
• Rhodium Catalyzed Transformation of 4-Pentynyl Cyclopropanes to Bicyclo[4.3.0]nonenones via Cleavage of Cyclopropane Ring
• Preparation of 1,4-Dicyanobenzene Derivatives and the Substituent Effect of the Sensitizers of Photoinduced Electron-Transfer Reactions
• Generation of β-Keto Radicals from Cyclopropanols Catalyzed by AgNO_3
• Rhodium-Catalyzed Intramolecular Pauson-Khand Reaction
• Intermolecular Allene-Alkyne Coupling Reactions by the Use of Fe(CO)_4(NMe_3)
• Generation of α-Alkylthio Radicals by Photoinduced One-Electron Oxidation of α-Stannyl Sulfides and Their Use for Carbon-Carbon Bond Formation
• Sulfonylation and Phosphinylation of Olefinic Compounds with Radical Species Generated by the Oxidation of Sodium Sulfinates and Diphenylphosphine Oxide
• Generation of Sulfonyl Radicals from Sodium Sulfinates by Oxidation with Metallic Oxidants and Their Addition Reaction with Olefins
• Rhodium-Catalyzed Acylation of Vinylsilanes with Acid Anhydrides
• Rhodium-Catalyzed Acylation of Vinylsilanes with Acid Anhydrides : Application to the Transformation of α-Acyloxy Vinylsilanes to Unsymmetrical 1, 2-Diketones
• Development of New Methods for Generation of Radical Species by One-Electron Oxidation with Metallic Oxidants toward Construction of Carbon Skeletons
• Generation of Cation Radicals from 2-Tributylstannyl-1,3-dithianes and Their Reaction with Olefins
• Oxidative Generation of 1-Nitroalkyl Radicals and Their Addition Reaction to Olefins^#
• Generation of Ary Radicals by the Oxidation of α-(Arylazo)triphenylmethanes by Cerium(IV) Ammonium Nitrate
• Generation of Nitrile Oxides from Oxime Derivatives by the Oxidation with Ammonium Hexanitratocerate(IV)
• Generation of α-Nitroalkyl Radicals by Oxidation of Nitronate Anions with Cerium(IV) Ammonium Nitrate and Their Addition Reaction to Electron-Rich Olefins
• Synthesis of Peduncularine
• P-178 TOTAL SYNTHESIS OF PEDUNCULARINE
• Generation of Cation Radicals from Enamines and Their Reactions with Olefines
• P-407 Synthesis of (-)-Sordarin
• Synthesis of (±)-Sordaricin
• Synthesis of 1-Azaazulenes from Cycloheptatrienylmethyl Ketone O-Pentafluorobenzoyloximes by Palladium-Catalyzed Cyclization and Oxidation
• Synthesis of Primary Amines and N-Methylamines by the Electrophilic Amination of Grignard Reagents with 2-Imidazolidinone O-Sulfonyloxime
• Palladium-Catalyzed Synthesis of 1-Azaazulenes from Cycloheptatrienylmethyl Ketone O-Pentafluorovenoyl Oximes
• Synthesis of Dihydropyrrole and Pyrrole Derivatives by Radical Cyclization of γ, δ-Unsaturated Ketone O-Acetyloximes
• Synthesis of 3,4-Dihydro-2H-pyrroles from γ,δ-Unsaturated Ketone O-Acetyloximes
• Synthesis of a Bis(boronate) Compound Having s-Indacene Framework and Its Property as a Host Molecule for Dimethylaminopyridine
• Rhodium(I)-Catalyzed Acylation of Alkyne with Acylsilane: Transformation of 5- or 6-Alkynoylsilane to α-Alkylidenecycloalkanone
• Photochemical Transformation of γ, δ-Unsaturated Ketone O-(p-Cyanophenyl) oximes to 3, 4-Dihydro-2H-pyrrole Derivatives
• Preparations of Furans from α-Bromo Ketones and Enol Ethers Catalyzed by a Rhenium(I) Nitrogen Complex
• The EtAlCl_2-Catalyzed Cargill Rearrangement of Bicyclo[n.2.0] Compounds Prepared by the [2+2] Cycloaddition of Cycloalkenones and 1-t-Butyldimethylsilyl-2-methylthioacetylene
• Amination of Arenes with N, N-Dimethyl-2-imidazolidinone O-Methoxyacetyloxime
• Hydroformylation of Monosubstituted Alkenes Catalyzed by W-Rh Bimetallic Complex
• Synthesis of Polycyclic Imines by Palladium-Catalyzed Domino Cyclization of Di- and Trienyl Ketone O-Pentafluorobenzoyloximes
• Friedel-Crafts Acylation of Arenes Catalyzed by Bromopentacarbonylrhenium(I)
• Synthesis of Pyrrole Derivatives by Palladium-Catalyzed Cyclization of γ, δ-Unsturated Ketone O-Pentafluorobenzoyloximes
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• Synthesis of Spiro [indoline-3, 2′-pyrrolidine] Derivatives from β-3-Indolyl Ketone Oximes
• Preparation of Bridgehead Substituted Bicyclo[3.3.0]octane Derivatives by the BF_3・OEt_2-Catalyzed Rearrangement of Bicyclo[3.2.1]oct-6-en-8-ols
• Double Acylation of Alkenes with Acylchromates Promoted by Cationic Pd(II)Complex
• Synthesis of Pyrrole Derivatives by the Heck-Type Cyclization of γ,δ-Unsaturated Ketone O-Pentafluorobenzoyloximes
• Development of New Methods for Generation of Radical Species by One-Electron Oxidation with Metallic Oxidants toward Construction of Carbon Skeletons
• Preparation of m-Acylphenol Derivatives by the Reaction of Tricarbonyl(cyclohexadienone)iron Complex and Higher Order Cuprates
• Preparation of Primary Amines by the Copper(I) Catalyzed Reaction of 4, 4'-Bis(trifluoromethyl)benzophenone O-Methylsulfonyloxime and Alkyl Grignard Reagents
• Cyclization of O-Pentafluorobenzoyloxime Having (diene)Fe(CO)_3Moiety
• Synthesis of Dihydropyrrole Derivatives by Copper-Catalyzed Cyclization of γ, δ-Unsaturated Ketone O-Methoxycarbonyloximes
• One-Pot Synthesis of Unsymmetrical Ketones by the Reaction of Decacarbonyldimanganese with Two Kinds of Alkyllithiums
• Conversion of 1-(ω-Alkynyl)-1, 2-propadienyl Sulfides to Bicyclic Dienones by the Use of Iron Carbonyl Complex
• Synthesis of Pyridine and Isoquinoline Derivatives by the Palladium-Catalyzed Cyclization of Olefinic Ketone O-Pentafluorobenzoyloximes
• Generation of Acyl Radicals from 1-Oxidoalkylidenechromium(0) Complexes by Treatment with Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II) and Their Reactions with Olefins
• Diels-Alder Reaction of 3-Metylthiofuran and Transformation of the Cycloadducts to Substituted Cyclohexenols
• Rh(II)-catalyzed Isomerization of 2-Aryl-2H-azirines to 2,3-Disubstituted Indoles
• Stereoselective Reduction of β-Hydroxy Ketones to 1, 3-Diols with the Aid of a Terphenyboronic Acid
• Asymmetric Diels-Alder reactions of an acrylic acid derivative using a chiral titanium catalyst.
• Asymmetric Reactions of Enamines with Methyl(E)-4-Oxo-4-(2-oxo-1,3-oxazolidin-3-yl)-2-butenoate by the Use of a Chiral Titanium Reagent.
• Enentio- and Diastereo-Selective Synthesis of (+)-Grandisol.
• The michael reaction of silyl enol ethers with .ALPHA.,.BETA.-unsaturated ketones and acetals in the presence of titanium tetraalkoxide and titanium tetrachloride.
• Stereoselective .BETA.-C- and .BETA.-S-glycosylation of 2-deoxyribofuranose derivatives controlled by the 3-hydroxy protective group.
• Selective 1,4-chiral induction in the reaction of enolates generated from t-butyl .DELTA.-hydroxy carboxylates.

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