Total Synthesis of 10-Isothiocyanatoguaia-6-ene

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概要

• 論文の詳細を見る
• 1994-09-05

著者

• Funahashi M

  Department Of Chemistry School Of Science The Uiniversity Of Tokyo

• Funahashi Masahiro

  Department Of Chemistry And Biotechnology School Of Engineering The University Of Tokyo

• IWASAWA Nobuharu

  Department of Chemistry, Faculty of Science, The University of Tokyo

• NARASAKA Koichi

  Department of Chemistry, School of Science, The University of Tokyo

• Iwasawa N

  Kanagawa Acad. Sci. And Technol.(kast) Kawasaki

• Iwasawa Nobuharu

  Department Of Chemistry Faculty Of Science The University Of Tokyo

• Narasaka Koichi

  Department Of Applied Chemistry Faculty Of Engineering Kyushu Institute Of Technology

関連論文

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• A Conformationally Controlled Regioselective Rearrangement of 2-Substituted 1-Alkynylcyclopropanols to 2-Cyclopenten-1-ones via Hexacarbonyldicobalt Complex
• Regioselective Synthesis of Quinolin-8-ols and 1, 2, 3, 4-Tetrahydroquinolin-8-ols by the Cyclization of 2-(3-Hydroxyphenyl)ethyl Ketone O-2, 4-Dinitrophenyloximes
• Regioselectivesynthesis of 8-Hydroxytetrahydroquinolines by the Cyclization of m-Hydroxyphenethyl Ketone O-2, 4-Dinitrophenyloximes
• Radical Cyclization of O-Pentafluorobenzoyloximes Having a (Cyclohexadiene)Fe(CO)_3 Moiety
• Transfomation of Oximes of Phenethy Ketone Derivatives to Quinolines and Azaspirotrienones Catalyzed by Tetrabutylammonium Perrhenate and Trifluoromethanesulfonic Acid
• Synthesis of Azaspirodienones via Intramolecular Cyclization of p-Hydroxybenzylacetone Oximes and Their Transformation into Quinolines
• Beckmann Rearrangement of Oximes Catalyzed with Tetrabutylammonium Perrhenate and ATrifluoromethanesulfonic Acid
• Synthesis of Quinolines via Intramolecular Cyclization of Benzylacetone Oxime Derivatives Catalyzed with Tetrabutylammonium Perrhenate(VII) and Trifluoromethanesulfonic Acid
• Beckmann Rearrangement Catalyzed by the Combined Use of Tetrabutylammonium Perrhenate(VII) and Trifluoromethanesulfonic Acid
• Synthesis of Terphenylboronic Acid Derivatives and Recognition of Anomers of 2-Deoxyribofuranoside
• Synthesis of α-Methoxy-α,β-unsaturated Esters by Iodine-oxidation of the Anions of Fischer-type Carbene Complexes
• Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(pyridine-2-carboxylate) and Its Application to Total Synthesis of 10-Isothiocyanatoguaia-6-ene
• Synthesis of Polycyclic Compounds by the Reaction of Co_2(CO)_6 Complexed 1-[o-(1-Alkynyl)phenyl]cyclopropanols
• Total Synthesis of 10-Isothiocyanatoguaia-6-ene
• Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(2-pyridinecarboxylate)
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• Photochemical Generation of Radical Species from α - Stannyl Ethers and Their Reaction with Conjugate Enones
• Synthesis of α-Carbolines from β-(3-Indolyl) Ketone O-2,4-Dinitrophenyloximes
• Substituent Effect of 1,4-Benzenedicarbonitriles as Sensitizers on the Photoinduced Electron Transfer Reactions in Alcohol
• Intramolecular Substitution Reaction of Lithium Alkylidene Carbenoids. Regioselective Synthesis of Indenes
• Palladium-Catalyzed Carboacylation of Alkenes by Using Acylchromates as Acyl Donors
• Palladium-Catalyzed Synthesis of α-Diketones from Acylchromates, Indoarenes, and Carbon Monoxide
• Palladium Catalyzed Coupling Reaction of Acylchromate Complexed and Allylic Bromides
• A Novel Rearrangement of Chromium Allyloxy(aryl) carbene Complexes Catalyzed by Pd(0)
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• Synthesis of (±)-Stemonamide by the Application of Oxidative Coupling Reactions of Stannyl Compounds with Silyl Enol Ethers
• Oxidative Generation of α-Radicals of Carbonyl Compounds from the α-Stannyl Derivatives and Their Reactions with Electron-Rich Olefins
• Generation of α-Radicals of Acetic Acid Derivatives from α-Stannyl Ester and Amide and Their Reactions with Electron-Rich Olefins
• Synthesis of Dihydropyrroles by the Intramolecular Addition of Alkylideneaminyl Radicals Generated from 0-2, 4-Dinitrophenyloximes of γ, δ-Unsaturated Ketones
• Synthesis of Dihydropyrroles and Tetrahydropyridines by the Intramolecular Cyclization of O-Methylsulfonyloximes Having an Active Methine Group
• Regioselective Acylation of (5-Alkylidene-1, 3-cyciohexadiene)tricarbonyliron Complexes by the Reaction with Organometallic Reagents
• Preparation of M-Acylaniline Derivatives by the Reaction of Tricarbonyl(cyclohexadienone O-benzyloxime)iron Complex and Higher Order Cuprates
• Asymmetric Total Synthesis of Epolactaene
• S_N2 Substitution on sp^2 Nitrogen of Protonated Oxime
• Bissilyl Ketone ; A Convenient Method for the Synthesis and Its Pd(0)Catalyzed Reaction with Alkenes and Alkynes
• W(CO)_5(L)-Catalyzed Construction of Cyclic Carbon Frameworks
• Generation of Radical Species From Cyclohexane-1,2-dione and the Reaction with Olefins : Preparation of 4,5-Dihydro-7 ( 6H ) -benzofuranone Derivatives
• Photoconductive Anisotropy in Smectic Liquid Crystalline Photoconductor, 2-(4'-Octylphenyl)-6-dodecyloxynaphthalene
• Rhodium Catalyzed Transformation of 4-Pentynyl Cyclopropanes to Bicyclo[4.3.0]nonenones via Cleavage of Cyclopropane Ring
• Preparation of 1,4-Dicyanobenzene Derivatives and the Substituent Effect of the Sensitizers of Photoinduced Electron-Transfer Reactions
• Generation of β-Keto Radicals from Cyclopropanols Catalyzed by AgNO_3
• Phthalimidomethyl Group. A New Protecting Group of Thiols
• Rhodium-Catalyzed Intramolecular Pauson-Khand Reaction
• Intermolecular Allene-Alkyne Coupling Reactions by the Use of Fe(CO)_4(NMe_3)
• Generation of α-Alkylthio Radicals by Photoinduced One-Electron Oxidation of α-Stannyl Sulfides and Their Use for Carbon-Carbon Bond Formation
• Sulfonylation and Phosphinylation of Olefinic Compounds with Radical Species Generated by the Oxidation of Sodium Sulfinates and Diphenylphosphine Oxide
• Generation of Sulfonyl Radicals from Sodium Sulfinates by Oxidation with Metallic Oxidants and Their Addition Reaction with Olefins
• Rhodium-Catalyzed Acylation of Vinylsilanes with Acid Anhydrides
• Rhodium-Catalyzed Acylation of Vinylsilanes with Acid Anhydrides : Application to the Transformation of α-Acyloxy Vinylsilanes to Unsymmetrical 1, 2-Diketones
• Development of New Methods for Generation of Radical Species by One-Electron Oxidation with Metallic Oxidants toward Construction of Carbon Skeletons
• Generation of Cation Radicals from 2-Tributylstannyl-1,3-dithianes and Their Reaction with Olefins
• Oxidative Generation of 1-Nitroalkyl Radicals and Their Addition Reaction to Olefins^#
• Generation of Ary Radicals by the Oxidation of α-(Arylazo)triphenylmethanes by Cerium(IV) Ammonium Nitrate
• Generation of Nitrile Oxides from Oxime Derivatives by the Oxidation with Ammonium Hexanitratocerate(IV)
• Generation of α-Nitroalkyl Radicals by Oxidation of Nitronate Anions with Cerium(IV) Ammonium Nitrate and Their Addition Reaction to Electron-Rich Olefins
• Synthesis of Peduncularine
• P-178 TOTAL SYNTHESIS OF PEDUNCULARINE
• Hole Transport of a Liquid-crystalline Phenylterthiophene Derivative Exhibiting the Nematic Phase at Ambient Temperature
• Generation of Cation Radicals from Enamines and Their Reactions with Olefines
• P-407 Synthesis of (-)-Sordarin
• Synthesis of (±)-Sordaricin
• Synthesis of 1-Azaazulenes from Cycloheptatrienylmethyl Ketone O-Pentafluorobenzoyloximes by Palladium-Catalyzed Cyclization and Oxidation
• Synthesis of Primary Amines and N-Methylamines by the Electrophilic Amination of Grignard Reagents with 2-Imidazolidinone O-Sulfonyloxime
• Palladium-Catalyzed Synthesis of 1-Azaazulenes from Cycloheptatrienylmethyl Ketone O-Pentafluorovenoyl Oximes
• Synthesis of Dihydropyrrole and Pyrrole Derivatives by Radical Cyclization of γ, δ-Unsaturated Ketone O-Acetyloximes
• Synthesis of 3,4-Dihydro-2H-pyrroles from γ,δ-Unsaturated Ketone O-Acetyloximes
• Rearrangement of 1-Alkynylcyclopropanol to 3-Substituted 2-Cyclopentenone Promoted by a Catalytic Amount of Octacarbonyldicobalt-Triphenylphosphite
• Synthesis of a Bis(boronate) Compound Having s-Indacene Framework and Its Property as a Host Molecule for Dimethylaminopyridine
• P-505 Efficient Synthesis of Pyrrolo[1,2-a]indole Derivatives Based on [3+2] Cycloaddition of Transition Metal-Containing Azomethine Ylides
• Isolation and Reaction of (Indolin-3-ylidene) pentacarbonyltungsten Generated from Tungsten-containing Azomethine Ylide
• Stereoselective Synthesis of (E) and (Z)-Vinylsilane by the Addition Reaction of Organometallic Regagent to Silyl-substituted Fischer-type Carbene Complex
• A Novel Rearrangement of 1-Alkynylcyclopropanol to 2-Cyclopenten-1-one via Dicobalt Hexacarbonyl Complex
• Tandem Cyclizations of Benzopyranylidenetungsten(0) Complexes with Electron-Rich Dienes for the Stereoselective Synthesis of Polycyclic Carbon Skeletons
• Stereoselective Synthesis of Medium-sized Cyclic Compounds through the Intramolecular Michael-type Reaction Utilizing Alkyne-Hexacarbonyldicobalt Complex Formation
• W(CO)_5(L)-catalyzed Cyclization of ω-Acetylenic Silyl Enol Ethers for the Preparation of Nitrogen-containing Cyclic Compounds
• Octacarbonyldicobalt Promoted Transformation of 1-(1,2-Propadienyl)cyclopropanols to 1,4-Hydroquinones
• Cycloaddition Reactions of Transition Metal-containing Benzopyrylium and Related Zwitterionic Intermediates
• Rhodium(I)-Catalyzed Acylation of Alkyne with Acylsilane: Transformation of 5- or 6-Alkynoylsilane to α-Alkylidenecycloalkanone
• Photochemical Transformation of γ, δ-Unsaturated Ketone O-(p-Cyanophenyl) oximes to 3, 4-Dihydro-2H-pyrrole Derivatives
• Preparations of Furans from α-Bromo Ketones and Enol Ethers Catalyzed by a Rhenium(I) Nitrogen Complex
• The EtAlCl_2-Catalyzed Cargill Rearrangement of Bicyclo[n.2.0] Compounds Prepared by the [2+2] Cycloaddition of Cycloalkenones and 1-t-Butyldimethylsilyl-2-methylthioacetylene
• Amination of Arenes with N, N-Dimethyl-2-imidazolidinone O-Methoxyacetyloxime
• Hydroformylation of Monosubstituted Alkenes Catalyzed by W-Rh Bimetallic Complex
• Synthesis of Polycyclic Imines by Palladium-Catalyzed Domino Cyclization of Di- and Trienyl Ketone O-Pentafluorobenzoyloximes
• Friedel-Crafts Acylation of Arenes Catalyzed by Bromopentacarbonylrhenium(I)
• Synthesis of Pyrrole Derivatives by Palladium-Catalyzed Cyclization of γ, δ-Unsturated Ketone O-Pentafluorobenzoyloximes
• Preparation of Primary Amines by the Alkylation of O-Sulfonyloximes of Benzophenone Derivatives with Grignard Reagents
• Synthesis of Spiro [indoline-3, 2′-pyrrolidine] Derivatives from β-3-Indolyl Ketone Oximes
• Preparation of Bridgehead Substituted Bicyclo[3.3.0]octane Derivatives by the BF_3・OEt_2-Catalyzed Rearrangement of Bicyclo[3.2.1]oct-6-en-8-ols
• Double Acylation of Alkenes with Acylchromates Promoted by Cationic Pd(II)Complex
• Synthesis of Pyrrole Derivatives by the Heck-Type Cyclization of γ,δ-Unsaturated Ketone O-Pentafluorobenzoyloximes
• Development of New Methods for Generation of Radical Species by One-Electron Oxidation with Metallic Oxidants toward Construction of Carbon Skeletons
• Preparation of m-Acylphenol Derivatives by the Reaction of Tricarbonyl(cyclohexadienone)iron Complex and Higher Order Cuprates
• Preparation of Primary Amines by the Copper(I) Catalyzed Reaction of 4, 4'-Bis(trifluoromethyl)benzophenone O-Methylsulfonyloxime and Alkyl Grignard Reagents
• Cyclization of O-Pentafluorobenzoyloxime Having (diene)Fe(CO)_3Moiety
• Synthesis of Dihydropyrrole Derivatives by Copper-Catalyzed Cyclization of γ, δ-Unsaturated Ketone O-Methoxycarbonyloximes
• Selective Intermolecular [2+2] Cycloaddition Reaction Using Platinum(II) Catalyst with Hollow-shaped Triethynylphosphine
• Synthesis, Structure, and Catalytic Activity of Palladium Complexes Bearing a Tridentate PXP-Pincer Ligand of Heavier Group 14 Element (X=Ge, Sn)
• Asymmetric hydrocyanation of aldehydes using chiral titanium reagents.

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