Electrospray-Deposited Poly(3,4-ethylenedioxythiophene):Poly(styrene sulfonate) for Poly(3-hexylthiophene):Phenyl-C61-Butyric Acid Methyl Ester Photovoltaic Cells

概要

論文の詳細を見る
Electrospray-deposited poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) was investigated using several solvent solutions as a hole-transporting layer for spin-coated poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C61 butyric acid methyl ester (P3HT:PCBM) mixture organic thin-film solar cells (OSCs). Among them, the uniform deposition of PEDOT:PSS films was realized using 70% N,N-dimethylformamide solvent solution. The P3HT:PCBM solar cells with electrospray-deposited PEDOT:PSS as a hole transport layer showed a relatively high performance with an open-circuit voltage V_{\text{oc}} of 0.47 V, a short-circuit current J_{\text{sc}} of 8.9 mA/cm2, a fill factor \mathit{FF} of 0.48, and a power conversion efficiency of 2.0%, which were almost the same as those with a spin-coated PEDOT:PSS layer. These findings imply that the electrospray-deposited PEDOT:PSS is a possible material for use as a hole transport layer for conjugated polymer-based OSCs.
2012-10-25