Nanopore Size Estimation by Electrochemical Impedance Spectroscopy Analysis
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概要
- 論文の詳細を見る
We present a simple and cost-effective approach by electrochemical impedance spectroscopy (EIS) for the accurate pore size estimation of silicon based nanopores. This method takes into account the capacitor effects of the electrical double layer and the resistor effects of the ion concentration inside the nanochannel. The nanopore impedance was modeled as the electrolyte resistance $R_{\text{s}}$ in series with a parallel ion diffusion circuit charge transfer resistance $R_{\text{f}}$ with a constant phase element (CPE) that models the behavior of the double layer. EIS analysis, which has been widely employed to measure the energy storage and dissipation properties of physico-chemical systems in a frequency domain, was adopted to obtain the impedance parameters of the nanopores. The nanopore size was then estimated from the impedance parameters. The accuracy of the estimated nanopore size was verified using an transmission electron microscope (TEM) image.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2008-09-25
著者
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Yu Ming-chang
Department Of Electrical Engineering Southern Taiwan University Of Technology
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Wang Gou-jen
Department Of Mechanical Engineering National Chung-hsing University
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Yu Ming-Chang
Department of Mechanical Engineering, National Chung-Hsing University, Taichung 402, Taiwan
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Chien Ming-Chun
Department of Mechanical Engineering, National Chung-Hsing University, Taichung 402, Taiwan
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Wang Gou-Jen
Department of Mechanical Engineering, National Chung-Hsing University, Taichung 402, Taiwan
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