Facile Fabrication and Photolectrochemical Properties of Porphyrin–Fullerene Assemblies by Self-Assembly and Surface Sol–Gel Processes
スポンサーリンク
概要
- 論文の詳細を見る
Ultrathin photoelectric conversion films consisting of a porphyrin–fullerene photoredox pair were fabricated by the combined use of room-temperature covalent-bonding and surface sol–gel processes. First, cysteamine was self-assembled on an indium–tin-oxide (ITO) electrode. The cysteamine-modified electrode was then immersed in C60 solution, giving immobilization of C60 via bond formation between the amino group of cysteamine and C60. Next, the C60-modified electrode was dipped in 2-ethanolamine solution to implant the hydroxy group to the immobilized C60 via the bond formation between C60 and the amino group; thus, the hydroxy group was exposed as the outermost layer. Then, Ti(OBu)4 and tetracarboxyporphyrin (TCPP) were alternately assembled on the C60 layer by the surface sol–gel process, to give an assembly of TCPP, titanium oxide species [Ti(O)], and C60 on the ITO electrode. The double layering of TCPP–Ti(O) was possible. The spectral characterization of the films was carried out. In the presence of sacrificial reagents, anodic photocurrents were generated from these modified electrodes. The incorporation of the C60 layer resulted in the substantial enhancement of the photocurrents as compared with that of the TCPP layer alone, suggesting effective electron-transfer reactions between TCPP and C60 that contribute to the photocurrent increase. The photocurrents increased by the double layering of the TCPP and Ti(O) layers.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2006-04-30
著者
-
Yamada Sunao
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
-
Matsuoka Ken-ichi
Department Of Materials Physics And Chemistry Graduate School Of Engineering Kyushu University
-
Kakutani Keitaro
Department Of Materials Physics And Chemistry Graduate School Of Engineering Kyushu University
-
Akiyama Tsuyoshi
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
-
Arakawa Taichi
Department Of Materials Physics And Chemistry Graduate School Of Engineering Kyushu University
-
Akiyama Tsuyoshi
Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
-
Miyazaki Akinobu
Department of Material Science and Engineering, School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
-
Kakutani Keitaro
Department of Materials Physics and Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
関連論文
- Acute Myocardial Ischemia Causes Local Glutamate Release via Retrograde Transport of Glutamate Transporters(Metabolism/Biochemistry/Energetics 1 (IHD), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
- PE-015 In Vivo Direct Monitoring of Postganglionic Vagal Nerve Activity on the Sinoatrial Node(PE003,Autonomic Nervous System (H),Poster Session (English),The 73rd Annual Scientific Meeting of The Japanese Circulation Society)
- Photocurrent properties of cis-di(thiocyanato)-bis(4,4'-dicarboxy-2,2'-bipyridine) ruthenium(II) monolayers on the gold surfaces
- Fabrication of a Photoelectrochemical Cell Using a Self-Assembled Monolayer of Tris(2, 2'-bipyrisine)ruthenium(II)-Viologen Linked Thiol on Multistructured Gold Nanoparticles
- A Photoresponsive Ruthenium Complex-Titanium Oxide-Viologen Film Prepared by the Combination of Self-Assembly and Surface Sol-Gel Processes
- Fabrication of Conjugated Polymer Hybrid Thin Films with Radially Oriented Aluminosilicate Nanofibers by Spin-Assembly
- PJ-302 Blockade of a7-Nicotinic Acetylcholine Receptors Attenuates Cardio-protective Effects of Donepezil in Rats with Extensive Myocardial Infarction(PJ051,Autonomic Nervous System (H),Poster Session (Japanese),The 73rd Annual Scientific Meeting of The J
- PJ-223 Angiotensin II Attenuates Vagal Stimulation-Induced Acetylcholine Release in the Ventricle(Autonomic nervous system-4, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Influence of magadiite dispersion states on the flammability of polystyrene and polyphenylene ether-polystyrene alloy nanocomposites
- X-Ray Absorption Spectral Studies on the Anion-Selectivity of a Ruthenium(II) Polypyridine Complex-Impregnated Polymer Ultrathin Film
- Use of micafungin versus fluconazole for antifungal prophylaxis in neutropenic patients receiving hematopoietic stem cell transplantation
- Novel Effects of Twin-tailed Cationic Surfactants on the Formation of Gold Nanorods
- Surface-Enhanced Nonresonance Raman Scattering of Rhodamine 6G Molecules Adsorbed on Gold Nanorod Films
- PJ-262 Cariporide Reduces Myocardial Norepinephrine Efflux and Myoglobin Release Evoked by Ischemia and Reperfusion(Myocardial ischemia/reperfusion, basic/clinical-5, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Differential Norepinephrine Release Mechanisms in the Ischemic Myocardium and Skeletal Muscle(Autonomic Nervous System 3 (H), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
- Routine high-performance liquid chromatographic determination of myocardial interstitial norepinephrine
- PE-265 Vagal Stimulation during Ischemic Period But Not Reperfusion Period Reduces Myocardial Myoglobin Release in the Ischemic Region(Myocardial ischemia-reperfusion, basic/clinical-4 (IHD) PE45,Poster Session (English),The 70th Anniversary Annual Scient
- Microdialysis Approach to Assessment of Rat Cardiac Sympathetic Nerve Ending Functions
- Acute myocardial ischemia totally damages vagal efferent function whereas partially damages vagal afferent and local acetylcholine releasing function
- Liquid chromatographic determination of myocardial interstitial epinephrine
- High-performance liquid chromatographic determination of myocardial interstitial dihydroxyphenylglycol
- OE-265 Cardiomyocytes Produce Acetylcholine in Response to Muscarinic Receptor Agonists : a Possible Mechanism for Cardioprotective Effects of Vagal Stimulation on Cardiomyocytes(Neurohumoral factors-1, The 71st Annual Scientific Meeting of the Japanese C
- PJ-590 Contribution of Catechol-O-methyltransferase to Changes in Myocardial Catecholamine Levels During Ischemia and Reperfusion(Autonomic Nervous System 4 (H) : PJ99)(Poster Session (Japanese))
- Enhanced Absorption and Emission in a Copper Phthalocyanine-Gold Nanoparticle System Assisted by Localized Surface Plasmon
- Shape Control of Fullerene Microparticles by Using Ethylenediamine
- Facile Fabrication of Gold Nanoparticle-Titanium Oxide Multilayer Assemblies by Surface Sol-Gel Processes
- Fabrication of a Novel Photoelectric Conversion Device Consisting of a Poly-3-dodecylthiophene Film and C_ Fullerene-Ethylenediamine Nanoparticles
- Facile Fabrication of Gold Nanoparticle-Titanium Oxide Alternate Assemblies by Surface Sol-Gel Process and Their Photoresponsive Properties
- Optical Second Harmonic Generation in Alternately Assembled Dye-Polyion Multilayers
- Comparison of Plasmonic Sensing between Polymer- and Silica-coated Gold Nanorods
- Expression of Plasmid DNA Released from DNA Conjugates of Gold Nanorods
- Gold Nanorod-sensitized Cell Death : Microscopic Observation of Single Living Cells Irradiated by Pulsed Near-infrared Laser Light in the Presence of Gold Nanorods
- Mitochondrial DNA sequence analysis of patients with 'atypical psychosis'
- Preparation and Photoelectrochemical Properties of a Self-Assembled Monolayer of a Ruthenium Tris(2,2'-bipyridine)-viologen 1:2 Linked Compound
- Enormous Size Growth of Thiol-passivated Gold Nanoparticles Induced by Near-IR Laser Light
- Nonlinear Optical Responses of Dialkoxyazobenzene Isomers Adsorbed to Interface between Heptane and Viologen-Modified Quartz Plates^1
- Charge - Transfer Interaction between Phenothiazine - and Viologen Moieties Adsorbed to Quartz - Solution Interface as Studied by Optical Second Harmonic Generation (SHG)^1
- Thermal Degradation Behavior of Polystyrene/Magadiite Nanocomposites Prepared by Surface-initiated Nitroxide-Mediated Radical Polymerization
- Magnetic Field Effects on Photocurrent Responses from Modified Electrodes with CdS Nanoparticles
- Immobilization of Gold Nanorods on the Glass Substrate by the Electrostatic Interactions for Localized Plasmon Sensing
- Dye Sensitization Effect on Photocurrent Generation of Porphyrin-Polythiophene Composite Films
- Fabrication and Photoelectrochemical Properties of Porphyrin-Fullerene Assemblies by Self-assembly and Surface Sol-Gel Processes
- Solid State Solar Cells of Polythiophene-Porphyrin Composite Films
- Characterization and evaluation of role of porphyrin moiety in meso-tetrathienylporphyrin-polythiophene composite film (Special issue: Solid state devices and materials)
- Recent Progress in Analytical SHG Spectroscopy
- Fabrication and characterization of copper oxides/fullerene solar cells prepared by an electrodeposition method
- Third Harmonic Generation from Quantum-State PbS Embedded in Langmuir-Blodgett Film Matrix
- Fabrication and Photocurrent Generation of Multilayer Assemblies Consisting of Silver-nanoparticles, Polydiacetylene, and Polyions
- Silver-Nanoparticle-Assisted Photocurrent Generation in Polythiophene--Fullerene Thin Films
- Structural Control of Three-dimensional Assemblies of Anisotropic Gold Nanoparticles Based on Their Different Shapes
- Electrostatic Interactions between Surfactants and Water Soluble Dyes at the Air/Water Interface as Studied by Second Harmonic Interferometry
- Dewetting Inhibition and Interfacial Structures of Silsesquioxane-terminated Polystyrene Thin Films
- Stabilization of Polystyrene Thin Films against Dewetting by Silsesquioxane-terminated Polystyrene Additives
- Synthesis and Frictional Properties of Poly(2,3-dihydroxypropyl methacrylate) Brush Prepared by Surface-initiated Atom Transfer Radical Polymerization
- Magnetic Field Effects on Photoelectrochemical Reactions of Porphyrin--Viologen Linked Compounds in an Ionic Liquid
- Facile Fabrication and Photocurrent Generation Properties of Electrochemically Polymerized Fullerene–Poly(ethylene dioxythiophene) Composite Films
- Effects of Hole Transport Layer on Photoelectrochemical Responses from Polythiophene--Porphyrin Composite Polymer Electrode
- Fabrication of Densely Packed Gold Nanoparticle Films and Their Fluorescence Enhancement Effect
- Characterization and Evaluation of Role of Porphyrin Moiety in meso-Tetrathienylporphyrin–Polythiophene Composite Film
- In-Situ Observation of Second Harmonic Lights from Amphiphilic Ruthenium (II) Tris(2,2'-bipyridine) Complex at Glass/Liquid Interface
- Applications of Strong Interactions between Photons and Molecules to Analytical Sciences
- LASER TWO-PHOTON PHOTOIONIZATION DETECTION OF AROMATIC HYDROCARBONS IN REVERSED-PHASE HIGH PERFORMANCE LIQUID CHROMATOGRAPHY
- A DOUBLE-BEAM METHOD FOR TWO-PHOTON IONIZATION DETECTION IN LIQUID CHROMATOGRAPHY
- LASER TWO-PHOTON IONIZATION TECHNIQUE FOR A HIGH SENSITIVE DETECTION OF PYRENE
- Novel Photoelectrochemical Cell Using a Self-Assembled Monolayer of a Ruthenium (II) Tris(2,2'-bipyridine) Thiol Derivative : Short Note
- End-to-end Assemblies of Gold Nanorods Adsorbed on a Glass Substrate Modified with Polyanion Polymers
- A 10-year-old Girl with Obsessive-Compulsive Disorder:Discussed in terms of Families Having Marital Difficulties and Expatriate Children
- Photoelectrochemical Responses of Gold Electrodes Co-modified with Sulfur-Containing Ruthenium Tris(2,2'-bipyridine) and Viologen Derivatives
- A Porphyrin - Anchored Ultrathin Poly(vinylchloride) Film : Asymmetric Surface Property as Revealed by Interactions with 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone
- Correlation of Partition Coefficients of Enzymes and Amino Acids in Dextran+Poly(ethylene glycol)+Water Aqueous Two-Phase Systems
- Correlation of Liquid-Liquid Equilibria for Dextran+Poly(ethylene glycol)+Water Aqueous Two-Phase Systems
- Tuning Optical Properties of Two-Dimensional Ordered Arrays of Silica/Gold and Silver Core/Shell Structured Nanoparticles in Near-Infrared Region (Special Issue : Solid State Devices and Materials (2))
- Organic Solar Cells Based on Electrodeposited Polyaniline Films (Special Issue : Solid State Devices and Materials (2))
- Effects of Film Thickness on the Photocurrent Generation from Polythiophene-Fullerene Thin Films Containing Silver Nanoparticles (Special Issue : Solid State Devices and Materials (1))
- Structural Characterization and Photoelectrochemical Properties of Gold Nanoparticle Multistructures Prepared by Layer-by-Layer Deposition
- Medetomidine, an α2-Adrenergic Agonist, Activates Cardiac Vagal Nerve Through Modulation of Baroreflex Control
- Solid-State Solar Cells Consisting of Polythiophene-Porphyrin Composite Films
- Formation of Gold Nanorod–Myoglobin Aggregates by Electrostatic Interactions and Their Photochemical Properties
- Dichroism of Poly(vinylalcohol) Films Containing Gold Nanorods Induced by Polarized Pulsed-Laser Irradiation
- Fabrication and Photoelectrochemical Properties of Polythiophene-Porphyrin Composite Films
- Facile Fabrication and Photolectrochemical Properties of Porphyrin–Fullerene Assemblies by Self-Assembly and Surface Sol–Gel Processes
- Facile Fabrication of Gold Nanoparticle–Titanium Oxide Alternate Assemblies by Surface Sol–Gel Process
- Dependence on Electrode Potential of the Magnetic Field Effect on Photoelectrochemical Reactions of Electrodes Modified with Porphyrin–Viologen Linked Compounds
- Incorporation Effect of Silver Nanoparticles on Inverted Type Bulk-Heterojunction Organic Solar Cells
- Structural Characterization and Photocurrent Properties of cis-di(thiocyanato)-bis(4,4$'$-dicarboxy-2,2$'$-bipyridine) Ruthenium(II) Monolayers on the Gold Surfaces
- Orientation of Nanowires Consisting of Poly(3-butylthiophene) Using Strong Magnetic Field
- Microstructures and Photovoltaic Properties of Polysilane-Based Solar Cells
- Fabrication and Characterization of ZnO/Cu
- Purification and Substrate Specificity of A Ginkgo biloba Glycosidase Active in β-1,2-Xylosidic Linkage in Plant Complex Type N-Glycans
- Mixing Effect of Gold and Silver Nanoparticles on Enhancement in Performance of Organic Thin-Film Solar Cells
- Transition-metal complexes of pyrrole pigments. XIX. Electrochemical and coordination behaviors of (5,10,15,20-tetraphenylporphinato)niobium(V) complexes.
- Transition-metal complexes of pyrrole pigments. XVII. Preparation and spectroscopic properties of corrole complexes.
- Effects of Magnetic Processing on Electrochemical and Photoelectrochemical Properties of Electrodes Modified with C60–Phenothiazine Nanoclusters
- Novel Method for Spatioselective Electroless Plating Catalyzed by Laser-Deposited Gold Nanoparticles
- Facile Solubilization and Photovoltaic Application of C_ Fullerene-Ethylenediamine Adduct
- Gold Nanorods Embedded in Titanium Oxide Film for Sensing Applications
- Incorporation Effect of Silver Nanoparticles on Inverted Type Bulk-Heterojunction Organic Solar Cells
- Metal and Metal Oxide Nanoparticles for Photoelectrochemical Materials and Devices