Facile Fabrication and Photocurrent Generation Properties of Electrochemically Polymerized Fullerene–Poly(ethylene dioxythiophene) Composite Films
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概要
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Fullerene–poly(ethylene dioxythiophene) (polyEDOT) composite films consisting of 3,4-ethyeledioxythiophene (EDOT) and a thiophene derivative of C60 fullerene (ThC60) or C60 fullerene were fabricated on a transparent indium–tin-oxide (ITO) electrode by electrochemical polymerization of the electrolyte solution of ThC60 (or C60) and EDOT. Incorporation of the C60 fullerene moiety in the polythiophene film was strongly suggested from absorption spectra of the composite film. We have found a higher degree of incorporation of the C60 fullerene moiety into the ThC60–polyEDOT film, as compared with the C60–polyEDOT film. In the presence of methylviologen as an electron acceptor, the as-prepared C60–polyEDOT and ThC60–polyEDOT composite films generated stable cathodic photocurrents in the 400–700 nm region with broad peaks. The photocurrent intensity and the internal photon-to-current quantum efficiency of the ThC60–polyEDOT composite film were considerably larger than those of C60–polyEDOT and polyEDOT films. The thiophene unit of ThC60 was confirmed to be quite effective for a stable incorporation of the C60 fullerene moiety in the film and a higher photocurrent generation.
- 2009-04-25
著者
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Yamada Sunao
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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Sugawa Kosuke
Department Of Materials Physics And Chemistry Graduate School Of Engineering Kyushu University
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Yoneda Hiroyuki
Department Of Mechanical Engineering Faculty Of Science And Engineering Kinki University
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Akiyama Tsuyoshi
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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Kohama Keiichi
Advanced Material Engineering Division, Toyota Motor Corporation, Susono, Shizuoka 410-1193, Japan
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Sugawa Kosuke
Department of Materials Physics and Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
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Fukuyama Toshihide
Department of Materials Physics and Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
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Takechi Kensuke
Battery & Cells Division, Secondary Battery Laboratory III, Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan
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Shiga Tohru
Battery & Cells Division, Secondary Battery Laboratory III, Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan
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Motohiro Tomoyoshi
Motohiro Special Research Laboratory, Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan
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Nakayama Hideki
Battery Research Division, Toyota Motor Corporation, Susono, Shizuoka 410-1193, Japan
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Shiga Tohru
Battery & Cells Division, Secondary Battery Laboratory III, Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan
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Takechi Kensuke
Battery & Cells Division, Secondary Battery Laboratory III, Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan
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Motohiro Tomoyoshi
Motohiro Special Research Laboratory, Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan
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Akiyama Tsuyoshi
Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
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Yoneda Hiroyuki
Department of Materials Physics and Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
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Yamada Sunao
Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
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