Characteristic Features of Molecular Structure and Packing of Organopolysilanes with Asymmetric Side Chains

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概要

• 論文の詳細を見る

• The molecular structure and packing of poly(methyl ethyl silane), [(CH3)Si(C2H5)]n, and poly(methyl $n$-propyl silane), [(CH3)Si(C3H7)]n, have been examined by the X-ray diffraction method. For poly(methyl ethyl silane), several configurations are possible for the arrangement of the C2H5 group, whereas the C3H7 groups stretch along one equivalent direction for poly(methyl $n$-propyl silane). In both cases, the molecular structure and packing are mostly determined by the intramolecular steric hindrance and van der Waals interaction between side chains, which is the same as that of polysilanes with symmetric side chains.

• Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
• 2005-01-15

著者

• Furukawa Shoji

  Graduate School Of Computer Science And Systems Engineering Kyushu Institute Of Technology

• Ohta Hidetaka

  Graduate School Of Computer Science And Systems Engineering Kyushu Institute Of Technology

• Furukawa Shoji

  Graduate School of Computer Science and Systems Engineering, Kyushu Institute of Technology, 680-4 Kawazu, Iizuka, Fukuoka 820-8502, Japan

• Ohta Hidetaka

  Graduate School of Computer Science and Systems Engineering, Kyushu Institute of Technology, 680-4 Kawazu, Iizuka, Fukuoka 820-8502, Japan

関連論文

• Orientation of Poly (di-hexyl silane) Thin Films(Evaluation of organic materials)
• Nonradiative Investigation of Photodecomposition of Poly(di-$n$-hexylsilane) Thin Films Using Piezoelectric Photothermal Spectroscopy
• Time Dependence of Optical Properties of Vacuum-Evaporated Poly(di-methyl silane) Thin Films
• Characteristic Features of Molecular Structure and Packing of Organopolysilanes with Asymmetric Side Chains

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