Thermally Stable Carbamates as Novel Photobase Generator
スポンサーリンク
概要
- 論文の詳細を見る
Six carbamates were prepared as novel photobase generators (PBGs), and their photo-reactivity and thermal stability were investigated. The introduction of an alkyl substituent into NH moiety in O-carbamoyloximes and/or the use of naphthalimide moieties instead of oxime moieties gave higher temperature of thermal decomposition (Tsub>d). These carbamates were photo-decomposed on irradiation at 254 nm, and the photolysis rates of oxime carbamates were higher than those of naphthalimide carbamates. The generation of amines from naphthalimide carbamates was confirmed by HPLC analysis of irradiated solutions. Although corresponding amines were not detected from oxime carbamates, the formation of 2-acetonaphthone was observed, suggesting the formation of the other type of basic compounds after photolysis. Films of poly(glycidyl methacrylate) containing oxime carbamates or naphthalimide.
- The Society of Photopolymer Science and Technology (SPST)の論文
The Society of Photopolymer Science and Technology (SPST) | 論文
- Influence of Solvent Vapor Atmospheres to the Self-assembly of Poly(styrene-b-dimethylsiloxane)
- Conventional Measurement Method of Film Resistance of Plasma-Polymerized Thin Films Using a High-Resistance Meter
- Synthesis and Optical Properties of Carbazole-Containing Donor-Acceptor Type Conjugated Polymers
- Novolak Resist Removal Using Laser (266/532nm)
- Evaluation of Fluorinated Diamond Like Carbon as Antisticking Layer by Scanning Probe Microscopy