Synthesis of Bio-based Monomer from Vegetable Oil Fatty Acids and Design of Functionalized Greener Polyester
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概要
- 論文の詳細を見る
In order to design sustainable materials from vegetable oils-based fatty acids, we propose herewith the method to obtain unsaturated dicarboxylic acids as a polymerizable monomer through metathesis reaction of oleic and linoleic acids with 2nd generation Grubbs catalyst. Subsequently, functional green polyester was produced from dicarboxylic acids and aromatic diol. Dicarboxylic acid having similar structure i.e. Octadec-9-enedioic acid was successfully obtained from metathesis of both oleic and linoleic acids. Condensation polymerization of octadec-9-enedioic acid with 1, 6-hexanediol and 4, 4'-biphenol was carried out and it was shown that polymer with aromatic backbone had higher glass transition temperature compared to aliphatic polyester.
- 公益社団法人 日本化学会の論文
著者
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Shirai Yoshihito
Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology
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Shirai Yoshihito
Graduate School Of Life Science And System Engineering Kyushu Institute Of Technology
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Hassan Mohd
Department of Bioprocess Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia
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Ariffin Hidayah
Department of Bioprocess Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia
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Rahim Noor
Department of Bioprocess Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia
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Watanabe Kohtaro
Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology
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Andou Yoshito
Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology
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