Synthesis, Structure, and NMR Spectra of (Cu2(phen)2-(.MU.-(C6H5)2PCH2P(C6H5)2)2)(PF6)2 and Its Derivatives.
スポンサーリンク
概要
- 論文の詳細を見る
The bis(diphenylphosphino)methane(dppm) compounds of copper(I), [Cu<SUB>2</SUB>(μ-dppm)<SUB>2</SUB>(biL)<SUB>2</SUB>](PF<SUB>6</SUB>)<SUB>2</SUB> (biL=1,10-phenanthroline and its derivatives), have been synthesized and characterized by <SUP>1</SUP>H and <SUP>31</SUP>P NMR spectroscopy and X-ray crystallography. The molecules are found to contain a [Cu<SUB>2</SUB>(dppm)<SUB>2</SUB>]<SUP>2+</SUP> framework with the two copper atoms bridged by two dppm ligands to give eight-membered C<SUB>2</SUB>P<SUB>4</SUB>C<SUB>2</SUB> rings. This framework shows a staggered conformation subject to the coordination of additional ligands, biL. The coordination <SUP>1</SUP>H and <SUP>31</SUP>P shifts of the dppm are well-correlated with the basicity of the nitrogen donor atom of biL, sensitive to variations in the copper-ligand binding as well as their metal-to-ligand charge-transfer band. Crystallographic data of [Cu<SUB>2</SUB>(dppm)<SUB>2</SUB>(phen)<SUB>2</SUB>] are as follows, monoclinic space group <I>P</I>2<SUB>1</SUB>⁄<I>c</I>, <I>a</I>=11.515(2) Å, <I>b</I>=27.922(4) Å, <I>c</I>=12.493(2) Å, β=107.68(1)°, <I>U</I>=3827(1) Å<SUP>3</SUP>, and <I>Z</I>=2.
- 公益社団法人 日本化学会の論文
著者
-
MARUYAMA HIDEKI
Department of Metabolic Medicine, Kumamoto University Medical School
-
Munakata Megumu
Department Of Chemistry Faculty Of Science And Technology Kinki University
-
Masuda Hideki
Institute Of High Polymer Research Faculty Of Textile Science And Technology Shinshu University
-
Kitagawa Susumu
Department Of Chemistry Faculty Of Science Tokyo Metropolitan University
-
Nakamura Masaki
Department Of Applied Physics Okayama University Of Science
-
Nakamura Masaki
Department of Chemistry, Kinki University
-
Wada Shigetoshi
Department of Chemistry, Kinki University
-
Maruyama Hideki
Department of Chemistry, Kinki University
-
Masuda Hideki
Institute for Molecular Science
関連論文
- The Role of Cognitive-Motor Function in Precipitation and Inhibition of Epileptic Seizures
- Pneumothorax caused by metastatic carcinoma of the breast
- Lymphoepithelioma-like Esophageal Carcinoma: Report of a Case
- Small Intestinal Metastasis from Esophageal Carcinoma Associated with Small Intestinal Obstruction : Report of a Case
- Esophageal Intramural Pseudodiverticulosis with Mallory-Weiss Syndrome : Report of a Case
- Effects of Replacement of Prolines with Alanines on the Catalytic Activity and Thermostability of Inorganic Pyrophosphatase from Thermophilic Bacterium PS-3
- Delayed Infection of a Lymphocele Following Mastectomy with Immediate Breast Reconstruction : Report of a Case
- Abrupt Conversion of Mixed-Valence State in Trinuclear Iron Cyanoacetate Complex
- Heat Capacity of a Layered Molecule-Based Ferrimagnet [Mn^(S-pnH)(H_2O)][Mn^(CN)_6]・2H_2O
- Magnetic Excitation in Artificially Designed Oxygen Molecule Magnet(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
- Functional Micropore Chemistry of Crystalline Metal Complex-Assembled Compounds
- MULTIPLE REGRESSION ANALYSIS OF SIXTEEN RISK FACTORS INCLUDING SERUM APOLIPOPROTEINS IN ANGIOGRAPHICALLY DOCUMENTED CORONARY ARTERY DISEASE
- A New Honeycomb Assemblage of a Trisdithiolene Vanadium(IV) Complex, (PPh_4)_2[V(dbddto)_3](C_6H_4Cl_2)(hexane)_
- Design and Construction of Coordination Polymers Based on the Topological Property of the Multidentate Ligand
- Radical Copolymerizations of Vinyl Monomers in a Porous Coordination Polymer
- Chiral Protonated Amino Acid Ester Discrimination by Acyclic Chiral Hosts Including D-Mannofuranose Moieties in Fast Atom Bombardment Mass Spectrometry Coupled with the Enantiomer Labeled Guest Method
- Potential involvement of p53 in ischemia/reperfusion-induced osteonecrosis
- Synthesis, Structure, and Reactivities of the η^1:η^6-μ_2-Aryl Alkynyl Diruthenium Complex. X-Ray Structure of [CP(PPh_3)_2Ru(η^1:η^6-μ_2-C≡CC_6H_4Me-p)RuCp*]PF_6(Cp=η_5-C_5H_5, Cp*=η_5-C_5Me_5)
- Synthesis and Crystal Structure of New Sulfate-Bridged Coordination Polymer, {(4, 4'-bpyH_2)[Fe_3(4, 4'-bpy)_3(SO_4)_4(H_2O)_6]・10H_2O}_n(4, 4'-bpy=4, 4'-Bipyridine).Three-Dimensional Network with Microporous Channels
- Novel Extended Linear Structure of Decavanadate Anions Linked by Bis(4 - Pyridinium) Disulfide (H_2dpds), {(H_2dpds)_2[V_O_(OH)_2]・10H_2O}_n
- Syntheses and Structures of Zn Coordination Polymers with 4, 4' - Bipyridine and 4, 4' - Azopyridine, Effect of Counter Anions on the Network System
- Heterodinuclear Complex Cp^*Ru(CO)_2 Co(CO)_4 (Cp^*=η^5-C_5Me_5) Induced Selective Dimerization of Terminal Alkynes
- Crystal Structure of a Tris(dithiolene)Vanadium(IV)Complex Having Unprecedented D_ Symmetry
- Evaluation of Chiral Amino Acid Discrimination by a Permethylated Cyclic Tetrasaccharide, cyclo-{→6)-α-D-Glcp-(1→3)-α-D-Glcp-(1→6)-α-D-Glcp-(1→3)-α-D-Glcp-(1→}, Using FAB Mass Spectrometry
- A New Self-Assembled Porphyrin-Silver(I) Network
- He II Thermal Counterflow near Superfluid Turbulent Transition : I. QUANTUM LIQUIDS AND SOLIDS : Superfluid Flow
- Solubility of ^4He in Liquid ^3He at Very Low Temperatures
- Solubility of ^4He in Liquid ^3He at Very Low Temperatures : I. QUANTUM LIQUIDS AND SOLIDS : Liquid ^4He and ^3He-^4He
- Syntheses, Crystal Structure, and Magnetic Properties of Mn_ Single-Molecule Magnets with Naphthalenecarboxylate Bridges, [Mn_O_(O_2CC_H_7)_(H_2O)_4] and Their Tetraphenyl-phosphonium Salts
- Gene Structure and Expression of Plastocyanin in the Green Alga Gonium pectorale
- THE DAMAGE AND APOPTOSIS IN THE INTEGUMENT OF ARMADILLIDIUM VULGARE CAUSED BY UV(Genetics)(Proceedings of the Seventy-Third Annual Meeting of the Zoological Society of Japan)
- Synthesis and Structure of Novel Vanadium(III)Compounds Having a Cyclic Core
- Accumulation of Plastocyanin mRNA Lacking 5'Region in the Green Alga Pediastrum boryanum Grown under Copper-Deficient Conditions
- Systematic Construction of Porous Coordination Pillared-layer Structures and Their Sorption Properties
- Syntheses and Crystal Structures of Novel Di- and Trinuclear Rhodium Complexes Bridged by Pyrazine
- Synthesis and Crustal Structure of New Salicylate-Bridged Coordination Polymer, [Cu_2(sal)_2(pyz)(MeOH)_2]_n
- Analysis of ^Ag MASNMR Chemical Shieldings Observed in Ag_xCu_I Crystals
- A Novel Mn_ Single-molecule Magnet with a μ_3-Methanesulfonate Bridge
- A Chemical Modification of a Mn_ Single-Molecule Magnet by Replacing Carboxylate Anions with Diphenylphosphate Anions
- Effects of Metal Doping on the Spin-Crossover Properties of an Iron(II) Complex with Extended π-Conjugated Schiff-Base Ligand Having an N_4O_2 Donor Set
- Abrupt Spin Transitions and LIESST Effects Observed in Fe^ Spin-crossover Complexes with Extended π-Conjugated Schiff-base Ligands Having N_4O_2 Donor Sets
- Tris (solvent) iridium complex supported by the η^5-penta-methylcyclopentadienyl ligand. Refinement of [Ir (η^5-C_5Me_5)(Me_2CO)_2(H_2O)] (BF_4)_2
- Crystal Structure of 1:1 Donor-Acceptor Complex between 9,10-Benzophenanthrene and 2,3,5,6-Tetrafluoro-1,4-benzoquinone
- Crystla Structure of η^5-Pentamethylcyclopentadienyl-η^6-toluene Rhodium Tetrafluoroborate, [Rh(Cp*)(η^6-C_6H_5Me)](BF_4)_2(Cp*=η^5-C_5Me_5)
- δ*_-π_L Odd Electron Delocalization onto Aromatic Bridging Ligands in a Paramagnetic Dirhodium Complex and Intermolecular π-Stack Interaction in Crystal
- Syntheses, Structures, and Magnetic Properties of Di-μ_3-Chloride-Bridged Tripalladium Compounds, [Pd_3(μ_3-Cl)_2(HqnS)_6]Cl_2 (HqnS = Quinoline-2(1H)-thione) and [Pd_3(μ_3-Cl)_2(Et_2dtc)_2(PPh_3)_2]・C_6H_6 (Et_2dtc = N, N'-Diethyldithiocarbamate)
- Unsymmetrical Oxygenation Products of [Pd(mnt)_2]^ : Syntheses and Crystal Structures of (Bu_4N)_2[Pd(mnt){O_2S_2C_2(CN)_2}] and One-Dimensional Coordination Polymer (Bu_4N)_2[AgPd(mnt){O_2S_2C_2(CN)_2}]_2(mnt=1,2-Dicyano-1,2-ethylenedithiolato)
- A Novel Two-Dimensional Copper(I) Coordination Polymer with Bridging TTF: Crystal Structure of [Cu(dmtpn)_2(TTF)_](ClO_4)(dmtpn:2,5-dimethylterephthalonitrile)
- Crystal Structure of Tetranuclear Palladium Complex Bridged by Bis(diphenylphosphino)methane, [Pd_4(μ-dppm)_4(μ-Cl)_2](ClO_4)_2・bpe
- Three-dimensional Ferromagnetic Frameworks of Syn-Anti-type Carboxylate-bridged Ni^ and Co^ Coordination Polymers
- Comparative X-Ray Studies of a Copper(I) Coordination Polymer with 1, 2, 4, 5-Tetramethylmercaptobenzene (tmmb), [(CuX)_2(tmmb)]n(X=Br, I)
- Crystal Structure of Dinuclear Copper(I) Complex with 1, 2, 4, 5-Tetramethylmercaptobenzene, [Cu(tmmb)I]_2
- Formation of a Ligand-based Mixed-valence Cluster Triggered by Dehydration Condensation of Semiquinonates with o-Phenylenediamines
- A Novel 3-D Open Coordination Polymeric Network Assembled from Silver(I) and 4,5-Bis(cyanoethylsulfanyl)-1,3-dithiole-2-thione with S…S Contacts
- A Novel Coordination Polymer Incorporating a Dimeric Silver Unit : Increasing Structural Dimensionality through Ag-Ag and Ag-Hetero Atom Interactions
- Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I)Nitrate Complex, [Pd_2(μ-dppm)_2(NO_3)_2]
- Redetermination of Crystal Structure of Bispotassium (μ-chloro)(bischloro)copper(I) K_2CuCl_3 with Infinite Chains
- Crystal Structure of Bis{cis-bis(diphenylphosphino)ethylene}palladium(0) Acetone Solvate
- A Homometallic Ferrimagnet Based on Mixed Antiferromagnetic and Ferromagnetic Interactions through Oxamato and Carboxylato Bridges
- Guest-induced Single-crystal-to-single-crystal Transformation in Copper Complexes of 1,3,5-Benzenetricarboxylic Acid and 4,4'-Bipyridine
- Synthesis of Imidazole-Containing Ligands and Studies on Metal Complexes
- Preparation of Porous Cobalt(II) 1,3.5-Benzenetricarboxylates : Product Dependence on the Reaction Solvent and Additive
- Chiral Recognition of α-Amino Esters on the Chiral Helical Surface of Zinc Bilinone
- Two New Coordination Polymers Based on Hexanuclear Metal Cluster Cores
- Crystal Engineering of 3D Porous Coordination Polymers through Hydrogen Bonding to Coordination from 1D Helical Chains
- Effect of Countercations on the Structural Isomerization of a Dianionic Diruthenium Complex with a Ligand-unsupported Ru-Ru Bond
- Nanocrystals of Coordination Polymers
- Copper regulated cytochrome c_6 expression in Pediastrum boryanum
- Crystal Engineering of Multidimensional Copper(I) and Silver(I) Coordination Supermolecules and Polymers with Functions
- Heat Capacity of a Layered Molecule-Based Ferrimagnet [MnII($S$-pnH)(H2O)][MnIII(CN)6]$\cdot$2H2O
- Possible Mechanism of Secondary Narcolepsy with a Long Sleep Time Following Surgery for Craniopharyngioma
- Synthesis and Adsorption Properties of Azulene-containing Porous Interdigitated Framework
- Synthesis, Structure, and NMR Spectra of (Cu2(phen)2-(.MU.-(C6H5)2PCH2P(C6H5)2)2)(PF6)2 and Its Derivatives.
- Cardiovascular effects of nipradilol, a beta-adrenoceptor blocker with vasodilating properties.
- Structure, Electrical, and Mechanical Properties of Silver Nanocontacts
- Spectroscopic studies of copper(I) complexes of 1,8-di(2-pyridyl)-3,6-dithiaoctane in a nonaqueous solvent. The halide-ion effect on their structure.
- Nuclear magnetic resonance studies of copper(I) complexes of imidazoles. II Their reaction with ethylene, phosphite, and isocyanides.
- Kinetic studies on the stability enhancement of mixed ligand copper(II) complexs with 2,2'-bipyridyl and acetylacetonate.
- The affinity for carbon monoxide, electrochemical and spectral properties of binuclear copper(I) complexes.
- Synthesis and X-Ray Crystal Structure of the Dicopper(I)Complex of 2-(Diphenylphosphino)pyridine(Ph2Ppy). (Cu2(.MU.-Ph2Ppy)2(CH3CN)2)(PF6)2.
- Controlled Encapsulation of Photoresponsive Macromolecules in Porous Coordination Polymer
- Surface Functionalization of Protein Crystals with Carbohydrate Using Site-selective Bioconjugation