Solvent assisted oxy-cope rearrangement of diastereomeric 1,5-hexadien-3-ols. A new industrial process for polyprenyl ketones.

スポンサーリンク

概要

• 論文の詳細を見る

• Oxy-Cope rearrangement of diastereomeric l,5-hexadien-3-ols, new key intermediates for terpenoids pio-duction in industrial scale, were investigated in neat systems and solvent assisted systems. Various solvents affecting the selectivity of [3,3]-shift were classified by means of NMR studies on hydroxyl proton exchange time.

著者

• FUJITA YOSHIJI

  Central Research Laboratories, Kuraray Co. Ltd.

• Fujita Yoshiji

  Central Research Laboratories Kuraray Co. Ltd.

• Nishida Takashi

  Central Research Laboratories, Kuraray Co. Ltd.

• Onishi Takashi

  Central Research Laboratories, Kuraray Co. Ltd.

• Amiya Shigetoshi

  Central Research Laboratories, Kuraray Co. Ltd.

関連論文

• A 6-ns 4-Mb CMOS SRAM with Offset-Voltage-Insensitive Current Sense Amplifiers(Special Issue on the 1994 VLSI Circuits Symposium)
• SYNTHESIS AND ANTI-HYPERCHOLESTEREMIC ACTION OF CHROMAN DERIVATIVES
• Solvent assisted oxy-cope rearrangement of diastereomeric 1,5-hexadien-3-ols. A new industrial process for polyprenyl ketones.
• A new efficient and stereoselective synthesis of ubiquinone-10.
• A convenient method for conversion of allylic chlorides to .ALPHA.,.BETA.-unsaturated aldehydes.
• New industrial synthesis of squalane.

スポンサーリンク