The transformations of terpene ketones by oxygen. I. The autoxidation of fukinone.

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概要

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• Fukinone, possessing a cisoid enone system, is susceptible to air oxidation. The oxidation products have been extensively examined and have been established as including diastereomeric epoxides, a hydroxy ketone (petasitolone), a lactol (8β-hydroxyeremophilenolide), and a peroxy hemiacetal. Also, the products were compared with those derived from the autoxidation of pulegone, a monoterpenic analogue of fukinone.

• 公益社団法人 日本化学会の論文

著者

• Naya Keizo

  Department of Chemistry, Faculty of Science, Kwansei Gakuin University

• Horinaka Akio

  Department of Chemistry, Faculty of Science, Kwansei Gakuin University

関連論文

• Sesquiterpenes from the rhizomes of Ligularia dentata Hara.
• The Photosensitized Oxygenation of Furanoeremophilanes. I. The Isomeric Hydroperoxides from Petasalbin and Their Transformations to Lactones
• The photosensitized oxygenation of furanoeremophilanes. II. The preparation and stereochemistry of the isomeric hydroperoxides and the corresponding lactones from furanofukinin and furanoeremophilane.
• The transformations of terpene ketones by oxygen. I. The autoxidation of fukinone.
• The transformations of terpene ketones by oxygen. II. The base-catalyzed autoxidation of pulegone and fukinone and their dihydro compounds.
• The Structure of Petasitolone, a New Constituent of Petasites japonicus Maxim
• The Structural Elucidation of Sesquiterpene Lactones from Petasites japonicus Maxim
• The Preparation of Fukinane, A New Skeletal Sesquiterpene Hydrocarbon

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