Photo-cycloaddition of indene to chlorofluoroethylenes and some reactions concerning the adducts.

スポンサーリンク

概要

• 論文の詳細を見る

• Benzophenone photo-sensitized addition of indene to chlorofluoroethylenes [trichlorofluoroethylene, 1,2-dichloro-1,2-difluoroethylene, 1,1-dichloro-2,2-difluoroethylene, chlorotrifluoroethylene, tetrafluoroethylene] afforded 6,6,7,7-tetrahalogeno-2,3-benzobicyclo[3.2.0]hept-2-enes as corresponding cycloadducts. The structure of the cycloadducts obtained from unsymmetrical chlorofluoroethylenes shows that the addition reaction proceeds with good regioselectivity. Some reactions such as oxidation, reduction, dechlorination, and halogenation of the cycloadducts were also examined.

• 公益社団法人 日本化学会の論文

著者

• Kimoto Hiroshi

  Government Industrial Research Institute, Nagoya

• Takahashi Kensuke

  Nagoya Institute of Technology

• Muramatsu Hiroshige

  Government Industrial Research Institute, Nagoya

• Muramatsu Hiroshige

  Government Industrial Research Institute

• Kimoto Hiroshi

  Government Industrial Research Institute

関連論文

• A 1H and 31P NMR study of phenylphosphonous dichloride partially oriented in a nematic phase.
• Photo-cycloaddition of indene to chlorofluoroethylenes and some reactions concerning the adducts.
• Syntheses of Fluorine-Containing Chromans: A Radical Cycloaddition of Phenyl Alkyl Ethers with Hexafluoropropene
• NMR studies of picolyl-type carbanions. VIII. Anions produced by reactions of alkyl-substituted pyridines with butyllithium.
• Syntheses and reactions of fluorine-containing aromatic ketones.
• NMR spectra of benzenes containing trifluoromethyl groups.
• Photochemical Trifluoromethylation of 1-Methylimidazoles and 1-Methylpyrroles Containing Methylthio Groups.
• 1H and 19F NMR spectra of some fluorocyclobutane derivatives.

スポンサーリンク