1,3-Dipolar cycloaddition reaction of vinyl azides with enamines. Synthesis of vinyltriazolines and vinyltriazoles.
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概要
- 論文の詳細を見る
Reaction of α- and β-azidostyrene with enamines gave vinyltriazolines regioselectively in moderate yields. 1-Pyrrolidinyl enamines reacted with α-azidostyrene more readily than piperidino or morpholino enamines. β-Azidostyrene was as reactive as azidobenzene while α-azidostyrene was much less reactive. Vinyltriazolines formed from enamines of ketones were deaminated to yield the corresponding vinyltriazoles.
- 公益社団法人 日本化学会の論文
著者
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Tomoda Shuji
Department Of Chemistry College Of Arts And Sciences The University Of Tokyo
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Nomura Yujiro
Department Of Chemistry College Of Arts And Sciences The University Of Tokyo:examination Method Sect
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Ito Masato
Department Of Applied Chemistry Graduate School Of Science And Engineering Tokyo Institute Of Techno
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Tomoda Shuji
Department of Chemistry, College of General Education, The University of Tokyo
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Nomura Yujiro
Department of Chemistry, College of General Education, The University of Tokyo
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Takeughi Yoshito
Department of Chemistry, College of General Education, The University of Tokyo
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