A facile reduction of copper(II) leading to formation of stable copper(I) complexes. Redox properties of four- and five-coordinate copper complexes.
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概要
- 論文の詳細を見る
Schiff bases derived from 2-pyridinecarbaldehyde and 1,6-hexanediamine or bis(2-aminoethyl) disulfide gave stable Cu(I) complexes instead of Cu(II) complexes by reactions with copper(II) per chlorate. The facile reduction of copper(II) has been discussed on the basis of systematic comparisons of redox and ESR properties of about 20 complexes of similar structures.
- 公益社団法人 日本化学会の論文
著者
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Nakahara Akitsugu
Institute Of Chemistry College Of General Education Osaka University
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Sakurai Takeshi
Institute For Molecular Science
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Kimura Masazo
Institute of Chemistry, College of General Education, Osaka University
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