Bis(cyclohexyl isocyanide)palladium(II) halides and their benzene complexes.

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概要

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• Bis(cyclohexyl isocyanide)palladium(II) chloride, PdCl<SUB>2</SUB>(C<SUB>6</SUB>H<SUB>11</SUB>NC)<SUB>2</SUB> (<B>1</B>) was prepared from PdCl<SUB>2</SUB>. The configuration of the complex <B>1</B> is cis with respect to the isocyanides. The isocyano group in one cyclohexyl isocyanide takes axial conformation to chair form cyclohexyl group, while another takes equatorial conformation. By recrystallization of <B>1</B> from benzene bis(cyclohexyl isocyanide)palladium(II) chloride-benzene, PdCl<SUB>2</SUB>(C<SUB>6</SUB>H<SUB>11</SUB>NC)<SUB>2</SUB>(C<SUB>6</SUB>H<SUB>6</SUB>)<SUB>2</SUB> (<B>2</B>) was prepared. IR spectrum of <B>2</B> shows a characteristic absorption at 700 cm<SUP>−1</SUP> which is due to the benzene incorporated in the complex. Similar benzene complex was also prepared from PdBr<SUB>2</SUB>.

• 公益社団法人 日本化学会の論文

著者

• Tsuji Jiro

  Basic Research Laboratories, Toray Industries Inc.

• Kitano Yukishige

  Basic Reseach Laboratories, Toray Industries, Inc.

• Kajimoto Tsunesuke

  Basic Research Laboratories, Toray Industries, Inc.

• Takahashi Hidetaka

  Basic Research Laboratories, Toray Industries, Inc.

• Kitano Yukishige

  Basic Research Laboratories, Toray Industries, Inc.

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• CuCl-catalyzed oxidative coupling reaction of secondary amines with molecular oxygen in pyridine.
• Bis(cyclohexyl isocyanide)palladium(II) halides and their benzene complexes.
• The Crystal Structure of Di-π-allyl(dihydropentalenylene)dinickel

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