CuCl-catalyzed oxidative coupling reaction of secondary amines with molecular oxygen in pyridine.

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概要

• 論文の詳細を見る

• Oxidation of diphenylamine with molecular oxygen in the presence of CuCl in pyridine at room temperature to give tetraphenylhydrazine in a high yield was achieved by selecting suitable reaction conditions. <I>N</I>-methylaniline was also oxidized to give <I>N</I>,<I>N</I>′-dimethyl-<I>N</I>,<I>N</I>′-diphenylhydrazine.

• 公益社団法人 日本化学会の論文

著者

• Tsuji Jiro

  Basic Research Laboratories, Toray Industries Inc.

• Kajimoto Tsunesuke

  Basic Research Laboratories, Toray Industries, Inc.

• Takahashi Hidetaka

  Basic Research Laboratories, Toray Industries, Inc.

関連論文

• Organic Syntheses by Means of Noble Metal Compounds. XLIX. Oxidation of 3-Hexenedioate to 2,4-Hexadienedioate Catalyzed by Palladium Chloride and Copper (II) Chloride
• CuCl-catalyzed oxidative coupling reaction of secondary amines with molecular oxygen in pyridine.
• Bis(cyclohexyl isocyanide)palladium(II) halides and their benzene complexes.

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