The Crystal Structure of Dichlorobis(acetoxime)palladium

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概要

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• The crystal structure of dichlorobis(acetoxime)palladium, PdCl<SUB>2</SUB>(C<SUB>3</SUB>H<SUB>6</SUB>NOH)<SUB>2</SUB>, has been determined from three-dimensional single-crystal X-ray photographic data. The crystals belong to the monoclinic system (space group P2<SUB>1</SUB>/a), with two formula units in a cell with dimensions: <I>a</I>=8.709±0.007, <I>b</I>=13.996±0.005, <I>c</I>=4.756±0.006 Å, and β=95.60±0.05°. The structure was established by the heavy-atom method and was refined by the block-diagonal least-squares procedure. The Pd atoms are spaced at intervals of 4.76 Å along the c-axis and have a <I>trans</I> planar coordination, with two Cl atoms at 2.30 Å and two N atoms of the oxime groups at 2.03 Å. The oxime plane is twisted about the Pd–N bond by 72.7° from the coordination plane defined by the Pd, Cl, and N atoms. The complex molecules are hydrogen-bonded with each other in strings of an indefinite length along the c-axis, and the hydrogen-bond distance between the O atom of the oxime and the Cl atom is 3.07 Å.

• 公益社団法人 日本化学会の論文

著者

• Tanimura Masamitsu

  Basic Research Laboratories, Toray Industries, Inc.

• Kobori Kiyotomi

  Basic Research Laboratories, Toray Industries, Inc.

• Kitano Yukishige

  Basic Reseach Laboratories, Toray Industries, Inc.

• Kinoshita Yukio

  Basic Research Laboratories, Toray Industries, Inc.

• Kinoshita Yukio

  Basic Reseach Laboratories, Toray Industries, Inc.

関連論文

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• The Crystal Structure of Dichlorobis(acetoxime)palladium
• Crystal Structure of Bis(nitrosocyclohexane)
• Bis(cyclohexyl isocyanide)palladium(II) halides and their benzene complexes.
• The Crystal Structure of Di-π-allyl(dihydropentalenylene)dinickel

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