The stereoselective Diels-Alder reaction of bicyclo(3.2.0)nona-3,6-dien-2-one with several dienes.

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概要

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• The <I>endo</I>-<I>cis</I> adducts were selectively obtained by the Diels-Alder reaction of several dienes with bicyclo[3.2.2]nona-3,6-dien-2-one, prepared from tropone and ethylene. This selective formation from the bicyclic dienophile, the isolated C=C and ethano C–C bonds of which are situated in similar sterical environments within the molecule, was supported by an Extended Hückel calculation.

• 公益社団法人 日本化学会の論文

著者

• MAMETSUKA Hiroaki

  Research Institute of Innovative Technology for the Earth

• Takeshita Hitoshi

  Research Institute of Industrial Science, 86, Kyushu University

• Hatsui Toshihide

  Research Institute of Industrial Science, Kyushu University

• Hatsui Toshihide

  Research Institute of Industrial Science, 86, Kyushu University

• Shimooda Isao

  Research Institute of Industrial Science, Kyushu University

• Mametsuka Hiroaki

  Research Institute of Industrial Sciece, 86, Kyushu University

• Takeshita Hitoshi

  Research Institute of Industrial Sciece, 86, Kyushu University

• Shimooda Isao

  Research Institute of Industrial Science, 86, Kyushu University

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