Synthetic photochemistry. XXIII. The photoreduction of dioxetanes to cis-1,2-glycols. 18O-Labelling experiments.
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概要
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The Rose Bengal-sensitized photooxidation of some dioxetane-forming olefins, the Diels-Alder dimer of spiroheptadiene, indene, acenaphthylene, and thujopsene, under an <SUP>18</SUP>O<SUB>2</SUB>-atmosphere yielded the labelled analogs of the previously characterized <I>cis</I>-1,2-glycols. According to the mass-spectral analysis, both oxygens of the glycols were derived from the oxygen molecule.
- 公益社団法人 日本化学会の論文
著者
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Takeshita Hitoshi
Research Institute of Industrial Science, 86, Kyushu University
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Hatsui Toshihide
Research Institute of Industrial Science, 86, Kyushu University
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