A photochemical storage battery with an n-GaP photoelectrode.
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概要
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We have constructed a photochemical storage battery with an <I>n</I>-GaP Photoelectrode. A two-compartment cell, <I>n</I>-GaP|aqueous K<SUB>3</SUB>[Fe(CN<SUB>6</SUB>]–K<SUB>4</SUB>[Fe(CN)<SUB>6</SUB>||aqueous NiSO<SUB>4</SUB>|Pt, is capable of being charged by the irradiation of the photoelectrode. The current efficiency of nickel deposition on the storage electrode was 80%. When we drew electrical energy out of the dattery, the deposited nickel could act as a Ni electrode in the Ni<SUP>2+</SUP> solution. The power efficiency of the storage battery amounted to about 2%. We could recharge the battery more than five times after discharge.
- 公益社団法人 日本化学会の論文
著者
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Hada Hiroshi
Department Of Neuropsychiatry Nippon Medical College
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YONEZAWA Yoshiro
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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Okai Makoto
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Ishino Masato
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Hada Hiroshi
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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