57Fe spin-lattice relaxation time of Fe(CO)5 and ferrocene.
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概要
- 論文の詳細を見る
Spin-lattice relaxation times (<I>T</I><SUB>1</SUB>'s) of <SUP>57</SUP>Fe were determined by the inversion recovery method to be 80 (±10) s at 293 K and 4 (±1) s at 303 K for Fe(CO)<SUB>5</SUB> and ferrocene, respectively. Predominant relaxation mechanisms were considered to be chemical shift anisotropy and spin-rotation for the former and the latter complexes, respectively.
- 公益社団法人 日本化学会の論文
著者
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SATO Mitsuo
Biophysics Division, Faculty of Pharmaceutical Sciences, Teikyo University
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Hatano Masahiro
Chemical Research Institure Of Non-aqueous Solutions Tohoku University
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NOZAWA TSUNENORI
Chemical Research Institute of Non-aqueous Solutions, Tohoku University
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Sato Mitsuo
Biophysics Division Faculty Of Pharmaceutical Sciences Teikyo University
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Toida Yoshiharu
Bruker Japan
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Batholdi Enrico
Bruker Japan
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