Pyridinium-1-thioacylaminides.
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概要
- 論文の詳細を見る
Pyridinium-, 2-methylpyridinium-, and 2,6-dimethylpyridinium-1-thioacylaminides (<B>5</B>–<B>7</B>) were prepared from the corresponding unsubstituted pyridinium-1-aminides and methyl dithiocarboxylates in fairly good yields. The alkylation reaction of <B>5</B>–<B>7</B> took place exclusively on the thiocarbonyl sulfur, yielding pyridinium salts in quantitative yields. The NMR spectroscopic studies indicated that <I>E</I> and <I>Z</I> forms existed for these pyridinium salts. The thermal decomposition of <B>5</B>–<B>7</B> yielded the corresponding pyridine, nitrile, and sulfur in good yields.
- 公益社団法人 日本化学会の論文
著者
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Yoshida Hiroshi
Departmen Of Radiology School Of Medicine Asahikawa Medical University
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Ogata Tsuyoshi
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Urushibata Kiyomi
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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