Photodimerization mechanism of m-methoxystyrene via its cation radical. Open type dimer cation radical as its intermediate.
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概要
- 論文の詳細を見る
Two isomeric tetralin type dimers were obtained by UV excitation of <I>m</I>-methoxystyrene in the presence of an electron acceptor. Stepwise electrophilic dimerization mechanism through the dimer cation radical was confirmed. The scheme was analyzed with the aid of MO calculation.
- 公益社団法人 日本化学会の論文
著者
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Yoshikawa Hiroaki
Department Of Electrical Engineering Osaka University
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Yamamoto Masahide
Department Of Hematology Tokyo Medical And Dental University
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Gotoh Tetsuya
Department Of Biology Faculty Of Science Yamagata University:(present Address)laboratory Of Cell And
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Nishijima Yasunori
Department of Chemistry Polytechnic Institute of Brooklyn
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Yoshikawa Hiroaki
Department of Polymer Chemistry, Faculty of Engineering, Kyoto University
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Gotoh Tetsuya
Department of Polymer Chemistry, Faculty of Engineering, Kyoto University
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Yamamoto Masahide
Department of Polymer Chemistry, Faculty of Engineering, Kyoto University
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