The cycloaddition reaction of N-imidoyl sulfoximides with diphenylcyclopropenone to yield pyrimidinone or pyrrolinone derivatives.
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概要
- 論文の詳細を見る
<I>N</I>-Imidoyl sulfoximide (<B>7</B>) reacted with diphenylcyclopropenone (<B>2</B>) at 130 °C to yield a mixture of 1,2-disubstituted 5,6-diphenyl-4(1<I>H</I>)-pyrimidinone (<B>6</B>) and <I>N</I>-(4-oxo-2-pyrrolin-5-yl)sulfoximide (<B>10</B>), which might be formed by [3+3] and [2+3] cycloaddition reactions between <B>2</B> and <B>7</B>. The yields of <B>6</B> and <B>10</B> depended on the electronic and steric effects of the substituents of <B>7</B>.
- 公益社団法人 日本化学会の論文
著者
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Yoshida Hiroshi
Departmen Of Radiology School Of Medicine Asahikawa Medical University
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Ogata Tsuyoshi
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Sogame Shingo
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Takishita Yasunori
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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