Photoreduction of 2-benzoylalkanoates.
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概要
- 論文の詳細を見る
2-Benzoylalkanoates <B>1</B> undergo photoreduction with 2-propanol. The photoreduction products are classified into three types according to their origin: the homo-pinacol-type products <B>2</B>, <B>5</B>, <B>7</B>, and <B>8</B>, the mixed-pinacol-type product <B>3</B>, and the β-hydroxy ester <B>6</B>. The product distribution is affected by α-methyl substitution. The α-methyl substitution decreases the percentage of the homo-pinacol-type products and increases the percentage of the β-hydroxy ester.
- 公益社団法人 日本化学会の論文
著者
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Aoki Satoshi
Department Of Biochemistry Faculty Of Science Josai University
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Yoshioka Michikazu
Department Of Chemistry Faculty Of Science Saitama University
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Hasegawa Tadashi
Department Of Cardiovascular And Thoracic Surgery Hakodate Municipal Hospital
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Shimizu Toshio
Department Of Chemistry Faculty Of Science Tokyo Metropolitan University
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Aoki Satoshi
Department of Chemistry, Saitama University
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Shimizu Toshio
Department of Applied Chemistry, Waseda University
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